This HTML5 document contains 44 embedded RDF statements represented using HTML+Microdata notation.

The embedded RDF content will be recognized by any processor of HTML5 Microdata.

Namespace Prefixes

PrefixIRI
dctermshttp://purl.org/dc/terms/
n16http://linked.opendata.cz/resource/domain/vavai/riv/tvurce/
n10http://linked.opendata.cz/resource/domain/vavai/projekt/
n17http://linked.opendata.cz/ontology/domain/vavai/
n12http://linked.opendata.cz/resource/domain/vavai/zamer/
n8http://linked.opendata.cz/resource/domain/vavai/vysledek/RIV%2F61388955%3A_____%2F10%3A00346411%21RIV11-MSM-61388955/
shttp://schema.org/
n4http://linked.opendata.cz/ontology/domain/vavai/riv/
skoshttp://www.w3.org/2004/02/skos/core#
n2http://linked.opendata.cz/resource/domain/vavai/vysledek/
rdfhttp://www.w3.org/1999/02/22-rdf-syntax-ns#
n11http://linked.opendata.cz/ontology/domain/vavai/riv/klicoveSlovo/
n18http://linked.opendata.cz/ontology/domain/vavai/riv/duvernostUdaju/
xsdhhttp://www.w3.org/2001/XMLSchema#
n13http://linked.opendata.cz/ontology/domain/vavai/riv/jazykVysledku/
n9http://linked.opendata.cz/ontology/domain/vavai/riv/aktivita/
n15http://linked.opendata.cz/ontology/domain/vavai/riv/druhVysledku/
n6http://linked.opendata.cz/ontology/domain/vavai/riv/obor/
n7http://reference.data.gov.uk/id/gregorian-year/

Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F10%3A00346411%21RIV11-MSM-61388955
rdf:type
skos:Concept n17:Vysledek
dcterms:description
Reaction of Ru(bpy)2Cl22 H2O with 1,2-bis(trifluoroacetyl)hydrazine H2(adc-CF3) under basic conditions yields the dinuclear [(μ-adc-CF3){Ru(bpy)2}2]2+ ion which was isolated and crystallized for structure determination in the meso diastereoisomer form as the bis(hexafluorophosphate). The Ru Ru distance was determined at 5.029(1) Å, and the N–N bond length at 1.463(5) Å reveals a hydrazido(2) form of the bridge, implying unchanged + II metal oxidation states. Besides bpy-based reduction, the cyclic voltammetric analysis revealed two oxidation waves with a (3+) intermediate. Spectroelectrochemistry demonstrated that this intermediate [(μ-adc-CF3){Ru(bpy)2}2]3+ with a comproportionation constant of Kc = 108.8 and an absorption at 1680 nm (ε = 9900 M-1 cm1) is a mixed-valent species as evident most convincingly from the EPR parameters at g1 = 2.239, g2 = 2.065, g3 = 1.891 (gav = 2.101, Δg = g1 g3 = 0.348). Reaction of Ru(bpy)2Cl22 H2O with 1,2-bis(trifluoroacetyl)hydrazine H2(adc-CF3) under basic conditions yields the dinuclear [(μ-adc-CF3){Ru(bpy)2}2]2+ ion which was isolated and crystallized for structure determination in the meso diastereoisomer form as the bis(hexafluorophosphate). The Ru Ru distance was determined at 5.029(1) Å, and the N–N bond length at 1.463(5) Å reveals a hydrazido(2) form of the bridge, implying unchanged + II metal oxidation states. Besides bpy-based reduction, the cyclic voltammetric analysis revealed two oxidation waves with a (3+) intermediate. Spectroelectrochemistry demonstrated that this intermediate [(μ-adc-CF3){Ru(bpy)2}2]3+ with a comproportionation constant of Kc = 108.8 and an absorption at 1680 nm (ε = 9900 M-1 cm1) is a mixed-valent species as evident most convincingly from the EPR parameters at g1 = 2.239, g2 = 2.065, g3 = 1.891 (gav = 2.101, Δg = g1 g3 = 0.348).
dcterms:title
Structure, electrochemistry and spectroscopy of a new diacylhydrazido-bridged diruthenium complex with a strongly near-infrared absorbing RuIIIRuII intermediate Structure, electrochemistry and spectroscopy of a new diacylhydrazido-bridged diruthenium complex with a strongly near-infrared absorbing RuIIIRuII intermediate
skos:prefLabel
Structure, electrochemistry and spectroscopy of a new diacylhydrazido-bridged diruthenium complex with a strongly near-infrared absorbing RuIIIRuII intermediate Structure, electrochemistry and spectroscopy of a new diacylhydrazido-bridged diruthenium complex with a strongly near-infrared absorbing RuIIIRuII intermediate
skos:notation
RIV/61388955:_____/10:00346411!RIV11-MSM-61388955
n4:aktivita
n9:Z n9:P
n4:aktivity
P(OC 140), P(OC09043), Z(AV0Z40400503)
n4:cisloPeriodika
10
n4:dodaniDat
n7:2011
n4:domaciTvurceVysledku
n16:3742121
n4:druhVysledku
n15:J
n4:duvernostUdaju
n18:S
n4:entitaPredkladatele
n8:predkladatel
n4:idSjednocenehoVysledku
290498
n4:idVysledku
RIV/61388955:_____/10:00346411
n4:jazykVysledku
n13:eng
n4:klicovaSlova
crystal structure; hydrazido ligand; near-infrared ruthenium
n4:klicoveSlovo
n11:crystal%20structure n11:hydrazido%20ligand n11:near-infrared%20ruthenium
n4:kodStatuVydavatele
NL - Nizozemsko
n4:kontrolniKodProRIV
[75AB446A912F]
n4:nazevZdroje
Inorganic Chemistry Communications
n4:obor
n6:CG
n4:pocetDomacichTvurcuVysledku
1
n4:pocetTvurcuVysledku
5
n4:projekt
n10:OC%20140 n10:OC09043
n4:rokUplatneniVysledku
n7:2010
n4:svazekPeriodika
13
n4:tvurceVysledku
Jana, R. Bubrin, D. Fiedler, Jan Kaim, W. Sarkar, B.
n4:wos
000281919700014
n4:zamer
n12:AV0Z40400503
s:issn
1387-7003
s:numberOfPages
3