This HTML5 document contains 50 embedded RDF statements represented using HTML+Microdata notation.

The embedded RDF content will be recognized by any processor of HTML5 Microdata.

Namespace Prefixes

PrefixIRI
dctermshttp://purl.org/dc/terms/
n13http://linked.opendata.cz/resource/domain/vavai/projekt/
n4http://linked.opendata.cz/resource/domain/vavai/riv/tvurce/
n14http://linked.opendata.cz/ontology/domain/vavai/
n18http://linked.opendata.cz/resource/domain/vavai/zamer/
shttp://schema.org/
skoshttp://www.w3.org/2004/02/skos/core#
n3http://linked.opendata.cz/ontology/domain/vavai/riv/
n2http://linked.opendata.cz/resource/domain/vavai/vysledek/
rdfhttp://www.w3.org/1999/02/22-rdf-syntax-ns#
n7http://linked.opendata.cz/resource/domain/vavai/vysledek/RIV%2F61388955%3A_____%2F09%3A00336726%21RIV10-MSM-61388955/
n10http://linked.opendata.cz/ontology/domain/vavai/riv/klicoveSlovo/
n15http://linked.opendata.cz/ontology/domain/vavai/riv/duvernostUdaju/
xsdhhttp://www.w3.org/2001/XMLSchema#
n12http://linked.opendata.cz/ontology/domain/vavai/riv/aktivita/
n8http://linked.opendata.cz/ontology/domain/vavai/riv/jazykVysledku/
n17http://linked.opendata.cz/ontology/domain/vavai/riv/druhVysledku/
n9http://linked.opendata.cz/ontology/domain/vavai/riv/obor/
n11http://reference.data.gov.uk/id/gregorian-year/

Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F09%3A00336726%21RIV10-MSM-61388955
rdf:type
skos:Concept n14:Vysledek
dcterms:description
Elimination of methane during thermolysis of title compounds results in the formation of sigma-Ti-C bond to t-butyl or benzyl group. The t-butyl-containing titanocene methyl compound [Ti(III)Me(eta(5)-C(5)Me(4)t-Bu)(2)] (5) eliminates methane at 110 degrees C to give cleanly [Ti(III)(eta(5):eta(1)-C5Me4CMe2CH2)(eta(5)-C(5)Me(4)t-Bu)] (6). The methyl derivative of analogous benzyl-containing titanocene [Ti(III)Me(eta(5)-C5Me4CH2Ph)(2)] was not isolated because it eliminated methane at ambient temperature to give [Ti(III)(eta(5):eta(1)-C5Me4CH2-o-C6H4)(eta(5)-C5Me4CH2Ph)] (7) with one phenyl ring linked to titanium atom in ortho-position. The corresponding titanocene dimethyl compound [TiMe2{eta(5)-C(5)Me(4)t-Bu)}(2)] (9) eliminates two methane molecules at 110 degrees C to give the singly tucked-in 1,1-dimethylethane-1,2-diyl-tethered titanocene [Ti{eta(5):eta(1):eta(1)-C5Me3(CH2)(CMe2CH2)}(eta(5)-C(5)Me(4)t-Bu)] (11). Elimination of methane during thermolysis of title compounds results in the formation of sigma-Ti-C bond to t-butyl or benzyl group. The t-butyl-containing titanocene methyl compound [Ti(III)Me(eta(5)-C(5)Me(4)t-Bu)(2)] (5) eliminates methane at 110 degrees C to give cleanly [Ti(III)(eta(5):eta(1)-C5Me4CMe2CH2)(eta(5)-C(5)Me(4)t-Bu)] (6). The methyl derivative of analogous benzyl-containing titanocene [Ti(III)Me(eta(5)-C5Me4CH2Ph)(2)] was not isolated because it eliminated methane at ambient temperature to give [Ti(III)(eta(5):eta(1)-C5Me4CH2-o-C6H4)(eta(5)-C5Me4CH2Ph)] (7) with one phenyl ring linked to titanium atom in ortho-position. The corresponding titanocene dimethyl compound [TiMe2{eta(5)-C(5)Me(4)t-Bu)}(2)] (9) eliminates two methane molecules at 110 degrees C to give the singly tucked-in 1,1-dimethylethane-1,2-diyl-tethered titanocene [Ti{eta(5):eta(1):eta(1)-C5Me3(CH2)(CMe2CH2)}(eta(5)-C(5)Me(4)t-Bu)] (11).
dcterms:title
Thermolysis of titanocene methyl compounds bearing t-butyl- and benzyltetramethylcyclopentadienyl ligands Thermolysis of titanocene methyl compounds bearing t-butyl- and benzyltetramethylcyclopentadienyl ligands
skos:prefLabel
Thermolysis of titanocene methyl compounds bearing t-butyl- and benzyltetramethylcyclopentadienyl ligands Thermolysis of titanocene methyl compounds bearing t-butyl- and benzyltetramethylcyclopentadienyl ligands
skos:notation
RIV/61388955:_____/09:00336726!RIV10-MSM-61388955
n3:aktivita
n12:Z n12:P
n3:aktivity
P(IAA400400708), P(LC06070), Z(AV0Z40400503), Z(MSM0021620857)
n3:cisloPeriodika
13
n3:dodaniDat
n11:2010
n3:domaciTvurceVysledku
n4:9689907 n4:7763743 n4:6327230 n4:7277962
n3:druhVysledku
n17:J
n3:duvernostUdaju
n15:S
n3:entitaPredkladatele
n7:predkladatel
n3:idSjednocenehoVysledku
346246
n3:idVysledku
RIV/61388955:_____/09:00336726
n3:jazykVysledku
n8:eng
n3:klicovaSlova
titanium; thermolysis; benzyltetramethylcyclopentadienyl
n3:klicoveSlovo
n10:thermolysis n10:benzyltetramethylcyclopentadienyl n10:titanium
n3:kodStatuVydavatele
CH - Švýcarská konfederace
n3:kontrolniKodProRIV
[0F9A765CBF46]
n3:nazevZdroje
Journal of Organometallic Chemistry
n3:obor
n9:CF
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
7
n3:projekt
n13:LC06070 n13:IAA400400708
n3:rokUplatneniVysledku
n11:2009
n3:svazekPeriodika
694
n3:tvurceVysledku
Mach, Karel Kubišta, Jiří Horáček, Michal Fandos, R. Pinkas, Jiří Cisařová, I. Conde, A.
n3:wos
000266270400003
n3:zamer
n18:MSM0021620857 n18:AV0Z40400503
s:issn
0022-328X
s:numberOfPages
10