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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F09%3A00335796%21RIV10-MSM-61388955
rdf:type
n4:Vysledek skos:Concept
dcterms:description
The neopentyl ester of 1,3-di(2-pyridyl) benzene-5-boronic acid (dpy-B) is a useful intermediate in the divergent synthesis of N<boolean AND>C<boolean AND>N-coordinating, 1,3-di(2-pyridyl) benzene ligands, HLn, that carry aryl substituents at the 5-position of the central ring. The platinum(II) complexes, (PtLCl)-Cl-n, of several such ligands have been prepared, incorporating pendant anisoles, arylamines, an oxacrown, and an azacrown, all of which are strongly luminescent in solution at 298 K. The emission of the complexes is partially quenched by oxygen, and all of the compounds are very efficient sensitisers of singlet oxygen. The quantum yields of O-1(2) formation have been measured on the basis of the intensity of the O-2 (1)Delta(g) emission at 1270 nm, and are in the range 0.25-0.65. The neopentyl ester of 1,3-di(2-pyridyl) benzene-5-boronic acid (dpy-B) is a useful intermediate in the divergent synthesis of N<boolean AND>C<boolean AND>N-coordinating, 1,3-di(2-pyridyl) benzene ligands, HLn, that carry aryl substituents at the 5-position of the central ring. The platinum(II) complexes, (PtLCl)-Cl-n, of several such ligands have been prepared, incorporating pendant anisoles, arylamines, an oxacrown, and an azacrown, all of which are strongly luminescent in solution at 298 K. The emission of the complexes is partially quenched by oxygen, and all of the compounds are very efficient sensitisers of singlet oxygen. The quantum yields of O-1(2) formation have been measured on the basis of the intensity of the O-2 (1)Delta(g) emission at 1270 nm, and are in the range 0.25-0.65.
dcterms:title
Localised to intraligand charge-transfer states in cyclometalated platinum complexes: an experimental and theoretical study into the influence of electron-rich pendants and modulation of excited states by ion binding Localised to intraligand charge-transfer states in cyclometalated platinum complexes: an experimental and theoretical study into the influence of electron-rich pendants and modulation of excited states by ion binding
skos:prefLabel
Localised to intraligand charge-transfer states in cyclometalated platinum complexes: an experimental and theoretical study into the influence of electron-rich pendants and modulation of excited states by ion binding Localised to intraligand charge-transfer states in cyclometalated platinum complexes: an experimental and theoretical study into the influence of electron-rich pendants and modulation of excited states by ion binding
skos:notation
RIV/61388955:_____/09:00335796!RIV10-MSM-61388955
n3:aktivita
n12:Z n12:P
n3:aktivity
P(OC 139), Z(AV0Z40400503)
n3:cisloPeriodika
10
n3:dodaniDat
n10:2010
n3:domaciTvurceVysledku
n17:3953084
n3:druhVysledku
n16:J
n3:duvernostUdaju
n9:S
n3:entitaPredkladatele
n5:predkladatel
n3:idSjednocenehoVysledku
323993
n3:idVysledku
RIV/61388955:_____/09:00335796
n3:jazykVysledku
n14:eng
n3:klicovaSlova
Cross-Coupling reactions; metal complexes; luminiscence
n3:klicoveSlovo
n7:metal%20complexes n7:Cross-Coupling%20reactions n7:luminiscence
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[03E19ED8763A]
n3:nazevZdroje
Dalton Transactions
n3:obor
n18:CG
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
4
n3:projekt
n15:OC%20139
n3:rokUplatneniVysledku
n10:2009
n3:svazekPeriodika
-
n3:tvurceVysledku
Williams, J. A. G. Develay, S. Záliš, Stanislav Rochester, D. L.
n3:wos
000263715100008
n3:zamer
n6:AV0Z40400503
s:issn
1477-9226
s:numberOfPages
14