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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F09%3A00329201%21RIV10-MSM-61388955
rdf:type
n13:Vysledek skos:Concept
dcterms:description
Cyclic voltammetry is used to study the transfer of a series of cations and anions across a room-temperature ionic liquid membrane composed of tridodecylmethylammonium cation and tetrakis[3,5-bis(trifluoromethyl) phenyl]borate anion. It is shown that the addition of water-soluble crown ether (e.g. 18-crown-6) to the aqueous phase makes it possible to distinguish the voltammetric responses of alkali and alkaline earth metal cations. The determination of low concentrations of K+ (0.05-0.3 mM) in the presence of an excess of Mg2+ (1 mM) in water is demonstrated as a model application of an amperometric ion-selective electrode for K+. Cyclic voltammetry is used to study the transfer of a series of cations and anions across a room-temperature ionic liquid membrane composed of tridodecylmethylammonium cation and tetrakis[3,5-bis(trifluoromethyl) phenyl]borate anion. It is shown that the addition of water-soluble crown ether (e.g. 18-crown-6) to the aqueous phase makes it possible to distinguish the voltammetric responses of alkali and alkaline earth metal cations. The determination of low concentrations of K+ (0.05-0.3 mM) in the presence of an excess of Mg2+ (1 mM) in water is demonstrated as a model application of an amperometric ion-selective electrode for K+.
dcterms:title
Amperometric Ion-Selective Electrode for Alkali Metal Cations Based on a Room-Temperature Ionic Liquid Membrane Amperometric Ion-Selective Electrode for Alkali Metal Cations Based on a Room-Temperature Ionic Liquid Membrane
skos:prefLabel
Amperometric Ion-Selective Electrode for Alkali Metal Cations Based on a Room-Temperature Ionic Liquid Membrane Amperometric Ion-Selective Electrode for Alkali Metal Cations Based on a Room-Temperature Ionic Liquid Membrane
skos:notation
RIV/61388955:_____/09:00329201!RIV10-MSM-61388955
n3:aktivita
n10:Z n10:P
n3:aktivity
P(IAA400400704), P(ME08098), Z(AV0Z40400503)
n3:cisloPeriodika
17-18
n3:dodaniDat
n4:2010
n3:domaciTvurceVysledku
n11:2681544 n11:5904196 n11:1415840
n3:druhVysledku
n15:J
n3:duvernostUdaju
n9:S
n3:entitaPredkladatele
n5:predkladatel
n3:idSjednocenehoVysledku
302655
n3:idVysledku
RIV/61388955:_____/09:00329201
n3:jazykVysledku
n18:eng
n3:klicovaSlova
room-temperature ionic liquid; alkali metals; Crown ether; cyclic voltammetry; amperometric ion-selective elkectrode
n3:klicoveSlovo
n7:cyclic%20voltammetry n7:room-temperature%20ionic%20liquid n7:alkali%20metals n7:Crown%20ether n7:amperometric%20ion-selective%20elkectrode
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[E32C37A8A1B2]
n3:nazevZdroje
Electroanalysis
n3:obor
n16:CG
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
3
n3:projekt
n12:ME08098 n12:IAA400400704
n3:rokUplatneniVysledku
n4:2009
n3:svazekPeriodika
21
n3:tvurceVysledku
Trojánek, Antonín Langmaier, Jan Samec, Zdeněk
n3:wos
000270399100013
n3:zamer
n14:AV0Z40400503
s:issn
1040-0397
s:numberOfPages
7