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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F09%3A00328669%21RIV10-AV0-61388955
rdf:type
n15:Vysledek skos:Concept
dcterms:description
Novel functionalized adsorbents for CO2 separation were synthesized by grafting 3-aminopropyl, 3-(methylamino)propyl, or 3-(phenylamino)propyl ligands in the delaminated zeolite ITQ-6. On the basis of the texture parameters determined from nitrogen adsorption isotherms recorded at 77 K and the results of chemical analysis, physicochemical properties of functionalized ITQ-6 were evaluated and compared with those of mesoporous SBA-15 silica functionalized with the same ligands. To examine carbon dioxide adsorption on functionalized materials, adsorption isotherms at 293 K were measured. To obtain information on the surface energetics of CO2 adsorption on selected samples, isotherms were taken in the temperature range from 273 to 333 K and adsorption isosteres were calculated. Isosteric adsorption heats determined from the slope of adsorption isosteres proved that all of the 3-aminopropyl ligands in ITQ-6 take part in CO2 adsorption. Novel functionalized adsorbents for CO2 separation were synthesized by grafting 3-aminopropyl, 3-(methylamino)propyl, or 3-(phenylamino)propyl ligands in the delaminated zeolite ITQ-6. On the basis of the texture parameters determined from nitrogen adsorption isotherms recorded at 77 K and the results of chemical analysis, physicochemical properties of functionalized ITQ-6 were evaluated and compared with those of mesoporous SBA-15 silica functionalized with the same ligands. To examine carbon dioxide adsorption on functionalized materials, adsorption isotherms at 293 K were measured. To obtain information on the surface energetics of CO2 adsorption on selected samples, isotherms were taken in the temperature range from 273 to 333 K and adsorption isosteres were calculated. Isosteric adsorption heats determined from the slope of adsorption isosteres proved that all of the 3-aminopropyl ligands in ITQ-6 take part in CO2 adsorption.
dcterms:title
Functionalization of Delaminated Zeolite ITQ-6 for the Adsorption of Carbon Dioxide Functionalization of Delaminated Zeolite ITQ-6 for the Adsorption of Carbon Dioxide
skos:prefLabel
Functionalization of Delaminated Zeolite ITQ-6 for the Adsorption of Carbon Dioxide Functionalization of Delaminated Zeolite ITQ-6 for the Adsorption of Carbon Dioxide
skos:notation
RIV/61388955:_____/09:00328669!RIV10-AV0-61388955
n4:aktivita
n5:Z n5:P
n4:aktivity
P(GA203/08/0604), Z(AV0Z40400503)
n4:cisloPeriodika
17
n4:dodaniDat
n12:2010
n4:domaciTvurceVysledku
n7:6088252 n7:7016662 Pérez-Dominguez, Irene n7:5283396
n4:druhVysledku
n16:J
n4:duvernostUdaju
n17:S
n4:entitaPredkladatele
n14:predkladatel
n4:idSjednocenehoVysledku
315726
n4:idVysledku
RIV/61388955:_____/09:00328669
n4:jazykVysledku
n9:eng
n4:klicovaSlova
zeolites; ITQ-6; carbon dioxide
n4:klicoveSlovo
n6:carbon%20dioxide n6:ITQ-6 n6:zeolites
n4:kodStatuVydavatele
US - Spojené státy americké
n4:kontrolniKodProRIV
[43C12065E543]
n4:nazevZdroje
Langmuir
n4:obor
n18:CF
n4:pocetDomacichTvurcuVysledku
4
n4:pocetTvurcuVysledku
4
n4:projekt
n10:GA203%2F08%2F0604
n4:rokUplatneniVysledku
n12:2009
n4:svazekPeriodika
25
n4:tvurceVysledku
Pérez-Dominguez, Irene Mayerová, Jana Zukal, Arnošt Čejka, Jiří
n4:wos
000269197500096
n4:zamer
n11:AV0Z40400503
s:issn
0743-7463
s:numberOfPages
8