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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F09%3A00327321%21RIV10-MSM-61388955
rdf:type
skos:Concept n16:Vysledek
dcterms:description
The paramagnetic compound [Ru(NO)(Q)(terpy)](PF6)2 (Q = 4,6-Di-tert.-butyl-N-phenyl-o-iminobenzoquinone) was prepared via the intermediates [RuCl(Q)(terpy)](ClO4) and [Ru(NO2)(Q)(terpy)](ClO4). The more stable positional isomer with NO trans to the O donor atom of Q was isolated and characterized. In conjunction with the X-ray crystal structure, IR and EPR studies suggest [RuII(NO+)(Q-)(terpy)]2+ as the most valid oxidation state formulation. DFT calculations confirm oxidation state assignment. The paramagnetic compound [Ru(NO)(Q)(terpy)](PF6)2 (Q = 4,6-Di-tert.-butyl-N-phenyl-o-iminobenzoquinone) was prepared via the intermediates [RuCl(Q)(terpy)](ClO4) and [Ru(NO2)(Q)(terpy)](ClO4). The more stable positional isomer with NO trans to the O donor atom of Q was isolated and characterized. In conjunction with the X-ray crystal structure, IR and EPR studies suggest [RuII(NO+)(Q-)(terpy)]2+ as the most valid oxidation state formulation. DFT calculations confirm oxidation state assignment.
dcterms:title
An Odd-Electron Complex [Ru-k(NOm)(Q(n))(terpy)](2+) with Two Prototypical Non-Innocent Ligands An Odd-Electron Complex [Ru-k(NOm)(Q(n))(terpy)](2+) with Two Prototypical Non-Innocent Ligands
skos:prefLabel
An Odd-Electron Complex [Ru-k(NOm)(Q(n))(terpy)](2+) with Two Prototypical Non-Innocent Ligands An Odd-Electron Complex [Ru-k(NOm)(Q(n))(terpy)](2+) with Two Prototypical Non-Innocent Ligands
skos:notation
RIV/61388955:_____/09:00327321!RIV10-MSM-61388955
n4:aktivita
n9:P n9:Z
n4:aktivity
P(KAN100400702), P(OC 139), Z(AV0Z40400503)
n4:cisloPeriodika
23
n4:dodaniDat
n13:2010
n4:domaciTvurceVysledku
n6:3742121 n6:3953084
n4:druhVysledku
n5:J
n4:duvernostUdaju
n17:S
n4:entitaPredkladatele
n8:predkladatel
n4:idSjednocenehoVysledku
302761
n4:idVysledku
RIV/61388955:_____/09:00327321
n4:jazykVysledku
n11:eng
n4:klicovaSlova
nitrosyl complexes; non-innocent ligands; quinones; radical ligands; ruthenium
n4:klicoveSlovo
n12:quinones n12:radical%20ligands n12:non-innocent%20ligands n12:nitrosyl%20complexes n12:ruthenium
n4:kodStatuVydavatele
DE - Spolková republika Německo
n4:kontrolniKodProRIV
[9D2EDBB1CDAF]
n4:nazevZdroje
Angewandte Chemie. International Edition in English
n4:obor
n15:CF
n4:pocetDomacichTvurcuVysledku
2
n4:pocetTvurcuVysledku
8
n4:projekt
n14:KAN100400702 n14:OC%20139
n4:rokUplatneniVysledku
n13:2009
n4:svazekPeriodika
48
n4:tvurceVysledku
Lahiri, G. K. Záliš, Stanislav Das, A. K. Fiedler, Jan Sarkar, B. Strobel, S. Kaim, W. Duboc, C.
n4:wos
000266527800036
n4:zamer
n18:AV0Z40400503
s:issn
1433-7851
s:numberOfPages
4