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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F09%3A00326731%21RIV10-AV0-61388955
rdf:type
skos:Concept n14:Vysledek
dcterms:description
Acetals/ketals derived from the aldehydes/ketones are easily prepared under solventless conditions. The process is heterogeneously catalysed using acid or basic mesoporous molecular sieves Al-SBA-15 and (Cs)Al-SBA-15. The catalytic procedure herein reported is applied to the preparation of the key intermediates for the synthesis of {3-[(2R,3R,4R,5R)-(2,3,4,5-tetrahydroxyhexane-1,6-diyl)]}di-1H-imidazole 2 with potential biomedical applications. Acetals/ketals derived from the aldehydes/ketones are easily prepared under solventless conditions. The process is heterogeneously catalysed using acid or basic mesoporous molecular sieves Al-SBA-15 and (Cs)Al-SBA-15. The catalytic procedure herein reported is applied to the preparation of the key intermediates for the synthesis of {3-[(2R,3R,4R,5R)-(2,3,4,5-tetrahydroxyhexane-1,6-diyl)]}di-1H-imidazole 2 with potential biomedical applications.
dcterms:title
Green Synthesis of Acetals/Ketals: Efficient Solvent-Free Process for the Carbonyl/Hydroxyl Group Protection Catalyzed by SBA-15 Materials Green Synthesis of Acetals/Ketals: Efficient Solvent-Free Process for the Carbonyl/Hydroxyl Group Protection Catalyzed by SBA-15 Materials
skos:prefLabel
Green Synthesis of Acetals/Ketals: Efficient Solvent-Free Process for the Carbonyl/Hydroxyl Group Protection Catalyzed by SBA-15 Materials Green Synthesis of Acetals/Ketals: Efficient Solvent-Free Process for the Carbonyl/Hydroxyl Group Protection Catalyzed by SBA-15 Materials
skos:notation
RIV/61388955:_____/09:00326731!RIV10-AV0-61388955
n3:aktivita
n13:P n13:Z
n3:aktivity
P(1QS400400560), Z(AV0Z40400503)
n3:cisloPeriodika
1-2
n3:dodaniDat
n4:2010
n3:domaciTvurceVysledku
n15:7016662 n15:5283396
n3:druhVysledku
n10:J
n3:duvernostUdaju
n17:S
n3:entitaPredkladatele
n9:predkladatel
n3:idSjednocenehoVysledku
316694
n3:idVysledku
RIV/61388955:_____/09:00326731
n3:jazykVysledku
n8:eng
n3:klicovaSlova
acid and basic heterogeneous catalysts; mesoporous molecular sieves; acatalation reactions; fine chemicals
n3:klicoveSlovo
n5:acatalation%20reactions n5:acid%20and%20basic%20heterogeneous%20catalysts n5:fine%20chemicals n5:mesoporous%20molecular%20sieves
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[080A6EDC8583]
n3:nazevZdroje
Topics in Catalysis
n3:obor
n16:CF
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
6
n3:projekt
n18:1QS400400560
n3:rokUplatneniVysledku
n4:2009
n3:svazekPeriodika
52
n3:tvurceVysledku
Zukal, Arnošt Čejka, Jiří Pérez-Mayoral, E. Martín-Aranda, R. M. Ballesteros, P. López-Peinado, A. J.
n3:wos
000263428100014
n3:zamer
n7:AV0Z40400503
s:issn
1022-5528
s:numberOfPages
5