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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F09%3A00322808%21RIV10-AV0-61388955
rdf:type
n11:Vysledek skos:Concept
dcterms:description
Mesoporous molecular sieves of various chemical composition, structural types, and dimensionality of their channels are interesting ordered materials with a high potential in adsorption but particularly in catalysis. This review covers various aspects of the catalytic behavior of mesoporous molecular sieves, in which these mesoporous molecular sieves operate both as catalysts or as catalyst supports for highly active oxidic or organometallic species. In the first part, examples of catalytic mesoporous molecular sieves are focused on single heteroatoms located in siliceous matrix as active sites for acid-catalyzed reactions, oxidation with hydrogen peroxide by Baeyer-Villiger reaction, Meerwein-Ponndorf-Verley reduction, esterification, and etherification. The second part describes catalytic systems based on mesoporous silica or alumina supports modified with transition metal oxides for hydrodesulfurization (MoO3) and metathesis of olefins and unsaturated esters (MoO3 or Re2O7). Mesoporous molecular sieves of various chemical composition, structural types, and dimensionality of their channels are interesting ordered materials with a high potential in adsorption but particularly in catalysis. This review covers various aspects of the catalytic behavior of mesoporous molecular sieves, in which these mesoporous molecular sieves operate both as catalysts or as catalyst supports for highly active oxidic or organometallic species. In the first part, examples of catalytic mesoporous molecular sieves are focused on single heteroatoms located in siliceous matrix as active sites for acid-catalyzed reactions, oxidation with hydrogen peroxide by Baeyer-Villiger reaction, Meerwein-Ponndorf-Verley reduction, esterification, and etherification. The second part describes catalytic systems based on mesoporous silica or alumina supports modified with transition metal oxides for hydrodesulfurization (MoO3) and metathesis of olefins and unsaturated esters (MoO3 or Re2O7).
dcterms:title
Catalysis by Mesoporous Molecular Sieves Catalysis by Mesoporous Molecular Sieves
skos:prefLabel
Catalysis by Mesoporous Molecular Sieves Catalysis by Mesoporous Molecular Sieves
skos:notation
RIV/61388955:_____/09:00322808!RIV10-AV0-61388955
n3:aktivita
n9:Z n9:P
n3:aktivity
P(GA104/05/0192), P(GA104/07/0383), P(GA203/05/0197), P(IAA400400805), P(IAA4040411), Z(AV0Z40400503)
n3:dodaniDat
n4:2010
n3:domaciTvurceVysledku
n20:7016662
n3:druhVysledku
n15:C
n3:duvernostUdaju
n6:S
n3:entitaPredkladatele
n19:predkladatel
n3:idSjednocenehoVysledku
305972
n3:idVysledku
RIV/61388955:_____/09:00322808
n3:jazykVysledku
n12:eng
n3:klicovaSlova
alkylations; acylations; catalysis; immobilization
n3:klicoveSlovo
n14:immobilization n14:acylations n14:alkylations n14:catalysis
n3:kontrolniKodProRIV
[B416137FDC61]
n3:mistoVydani
Oxford
n3:nazevZdroje
Ordered Porous Solids - Recent Advances and Prospects
n3:obor
n16:CF
n3:pocetDomacichTvurcuVysledku
1
n3:pocetStranKnihy
788
n3:pocetTvurcuVysledku
2
n3:projekt
n5:IAA4040411 n5:GA203%2F05%2F0197 n5:GA104%2F07%2F0383 n5:IAA400400805 n5:GA104%2F05%2F0192
n3:rokUplatneniVysledku
n4:2009
n3:tvurceVysledku
Vinu, A. Čejka, Jiří
n3:zamer
n13:AV0Z40400503
s:numberOfPages
19
n8:hasPublisher
Elsevier
n18:isbn
978-0-444-53189-6