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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F08%3A00315010%21RIV09-AV0-61388955
rdf:type
n13:Vysledek skos:Concept
dcterms:description
Řada homoleptických komplexů s non-innocent ligandy odvozených od N,N' -bis(pentafluorofenyl)-o-fenylenediamine (H2Fpda) je popsána. [NiII(Fsbqdi)2] (1), [PdII(Fsbqdi)2] (2), [CoII(Fsbqdi)2] (3), a [CuII(Fsbqdi)2] (4) byl syntetizovány, kde (Fsbqdi)1- reprezentuje radikálový anion vytvořený jednoelektronovou oxidací dvojnásobně deprotonovaného H2Fpda. Komplex 4 je první CuII komplex, kde oba o-fenylenediaminové ligandy jsou monoanionickými radikály. Elektronové struktury neutrálních sloučenin 1-4 a některých jejich kationických a anionických redox stavů byly prověřeny s použitím EPR a UV-VIS-NIR spektroelektrochemie. Zkroucená geometrie komplexů způsobuje značné změny v jejich elektronových strukturách ve srovnání se známými čtvercově-planárními komplexy. A series of homoleptic complexes with non-innocent ligands derived from N,N’ -bis(pentafluorophenyl)-o-phenylenediamine (H2Fpda) are reported. [NiII(Fsbqdi)2] (1), [PdII(Fsbqdi)2] (2), [CoII(Fsbqdi)2] (3), and [CuII(Fsbqdi)2] (4) were synthesized, where (Fsbqdi)1- represents a radical anion formed by one-electron oxidation of the doubly deprotonated H2Fpda. Complex 4 is the first CuII complex where both o-phenylenediamine derived ligands are monoanionic radicals. The electronic structures of the neutral compounds 1-4 and of some of their cationic and/or anionic neighboring redox states were probed using EPR and UV-VIS-NIR spectroelectrochemistry. The twisted geometry of the complexes results in considerable changes in their electronic structures compared to the well known square-planar complexes. A series of homoleptic complexes with non-innocent ligands derived from N,N’ -bis(pentafluorophenyl)-o-phenylenediamine (H2Fpda) are reported. [NiII(Fsbqdi)2] (1), [PdII(Fsbqdi)2] (2), [CoII(Fsbqdi)2] (3), and [CuII(Fsbqdi)2] (4) were synthesized, where (Fsbqdi)1- represents a radical anion formed by one-electron oxidation of the doubly deprotonated H2Fpda. Complex 4 is the first CuII complex where both o-phenylenediamine derived ligands are monoanionic radicals. The electronic structures of the neutral compounds 1-4 and of some of their cationic and/or anionic neighboring redox states were probed using EPR and UV-VIS-NIR spectroelectrochemistry. The twisted geometry of the complexes results in considerable changes in their electronic structures compared to the well known square-planar complexes.
dcterms:title
A series of metal complexes with the non-innocent N,N’-Bis(pentafluorophenyl)-o-phenylenediamido ligand: twisted geometry for tuning the electronic structure Řada kovových komplexů s non-innocent ligandem N,N'-Bis(pentafluorofenyl)-o-fenylendiamido: nastavení elektronové struktury vlivem zkroucené geometrie A series of metal complexes with the non-innocent N,N’-Bis(pentafluorophenyl)-o-phenylenediamido ligand: twisted geometry for tuning the electronic structure
skos:prefLabel
A series of metal complexes with the non-innocent N,N’-Bis(pentafluorophenyl)-o-phenylenediamido ligand: twisted geometry for tuning the electronic structure A series of metal complexes with the non-innocent N,N’-Bis(pentafluorophenyl)-o-phenylenediamido ligand: twisted geometry for tuning the electronic structure Řada kovových komplexů s non-innocent ligandem N,N'-Bis(pentafluorofenyl)-o-fenylendiamido: nastavení elektronové struktury vlivem zkroucené geometrie
skos:notation
RIV/61388955:_____/08:00315010!RIV09-AV0-61388955
n3:aktivita
n6:Z n6:P
n3:aktivity
P(OC 139), P(OC 140), Z(AV0Z40400503)
n3:cisloPeriodika
10
n3:dodaniDat
n12:2009
n3:domaciTvurceVysledku
n17:3742121
n3:druhVysledku
n11:J
n3:duvernostUdaju
n18:S
n3:entitaPredkladatele
n9:predkladatel
n3:idSjednocenehoVysledku
354491
n3:idVysledku
RIV/61388955:_____/08:00315010
n3:jazykVysledku
n10:eng
n3:klicovaSlova
metal complexes; non-innocent N,N’-Bis(pentafluorophenyl)-o-phenylenediamido ligand; electronic structure
n3:klicoveSlovo
n8:metal%20complexes n8:electronic%20structure n8:non-innocent%20N n8:N%E2%80%99-Bis%28pentafluorophenyl%29-o-phenylenediamido%20ligand
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[DB28372E9F32]
n3:nazevZdroje
Dalton Transactions
n3:obor
n15:CF
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
9
n3:projekt
n7:OC%20140 n7:OC%20139
n3:rokUplatneniVysledku
n12:2008
n3:svazekPeriodika
-
n3:tvurceVysledku
Sarkar, B. Fiedler, Jan Burghaus, O. Duboc, C. Kaim, W. Khusniyarov, M. M. van Slageren, J. Harms, K. Sundermayer, J.
n3:zamer
n16:AV0Z40400503
s:issn
1477-9226
s:numberOfPages
11