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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F08%3A00310179%21RIV09-AV0-61388955
rdf:type
n3:Vysledek skos:Concept
dcterms:description
Byla provedena detailní studie optických absorpčních vlastností tenkých filmů z jednostěnných uhlíkových nanotrubic. Dále byly studovány změny optické absorpce zmíněných filmů v závislosti na vloženém potenciálu. A detailed study is presented on the optical absorption of thin films of single wall carbon nanotubes (SWNT). The procedure for the preparation of free-standing semitransparent films of SWNT is used for the fabrication of a working electrode for transmission optical spectroelectrochemistry. The analysis of the potential dependent spectroscopic response of the SWNT film benefits from the widest possible electrochemical window, in which the charging of SWNT can safely be investigated. This electrochemical window is not limited by parasitic electrochemistry and/or galvanic breakdown reactions occurring at supporting electrode materials such as indium-tin oxide conducting glass or semitransparent Pt film, which were employed in earlier studies. Electrochemical doping of SWNT is observable at the optical absorptions, which are assigned to allowed electronic transitions between van Hove singularities in the density of states of SWNT. A detailed study is presented on the optical absorption of thin films of single wall carbon nanotubes (SWNT). The procedure for the preparation of free-standing semitransparent films of SWNT is used for the fabrication of a working electrode for transmission optical spectroelectrochemistry. The analysis of the potential dependent spectroscopic response of the SWNT film benefits from the widest possible electrochemical window, in which the charging of SWNT can safely be investigated. This electrochemical window is not limited by parasitic electrochemistry and/or galvanic breakdown reactions occurring at supporting electrode materials such as indium-tin oxide conducting glass or semitransparent Pt film, which were employed in earlier studies. Electrochemical doping of SWNT is observable at the optical absorptions, which are assigned to allowed electronic transitions between van Hove singularities in the density of states of SWNT.
dcterms:title
Optická spektroelektrochemie in situ měřená na tenkém filmu z jednostěnných uhlíkových nanotrubic In situ optical spectroelectrochemistry of single-walled carbon nanotube thin films In situ optical spectroelectrochemistry of single-walled carbon nanotube thin films
skos:prefLabel
In situ optical spectroelectrochemistry of single-walled carbon nanotube thin films Optická spektroelektrochemie in situ měřená na tenkém filmu z jednostěnných uhlíkových nanotrubic In situ optical spectroelectrochemistry of single-walled carbon nanotube thin films
skos:notation
RIV/61388955:_____/08:00310179!RIV09-AV0-61388955
n4:aktivita
n7:Z n7:P
n4:aktivity
P(LC510), Z(AV0Z40400503)
n4:cisloPeriodika
10
n4:dodaniDat
n10:2009
n4:domaciTvurceVysledku
n13:5808111 n13:1157744 n13:3189856 n13:9704418
n4:druhVysledku
n17:J
n4:duvernostUdaju
n18:S
n4:entitaPredkladatele
n14:predkladatel
n4:idSjednocenehoVysledku
371763
n4:idVysledku
RIV/61388955:_____/08:00310179
n4:jazykVysledku
n11:eng
n4:klicovaSlova
uv-vis spectroelectrochemistry; cyclic voltammetry; single-walled carbon nanotubes; thin films; doping
n4:klicoveSlovo
n12:thin%20films n12:single-walled%20carbon%20nanotubes n12:doping n12:cyclic%20voltammetry n12:uv-vis%20spectroelectrochemistry
n4:kodStatuVydavatele
DE - Spolková republika Německo
n4:kontrolniKodProRIV
[5931E27C012D]
n4:nazevZdroje
Journal of Solid State Electrochemistry
n4:obor
n5:CG
n4:pocetDomacichTvurcuVysledku
4
n4:pocetTvurcuVysledku
5
n4:projekt
n8:LC510
n4:rokUplatneniVysledku
n10:2008
n4:svazekPeriodika
12
n4:tvurceVysledku
Zukalová, Markéta Tarábek, Ján Dunsch, L. Kalbáč, Martin Kavan, Ladislav
n4:wos
000257208800009
n4:zamer
n16:AV0Z40400503
s:issn
1432-8488
s:numberOfPages
6