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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F07%3A00092692%21RIV08-MSM-61388955
rdf:type
skos:Concept n14:Vysledek
dcterms:description
We present an advanced study of the physical adsorption of pure fluids, such as argon and nitrogen, and water vapor, on novel micro/mesoporous zeolites Beta and ZSM-5 as well as on mesoporous molecular sieves (e.g. SBA-16). We demonstrate that combining the adsorption of nitrogen at 77.4 K and argon at 87.3 K with a systematic water vapor sorption study performed at temperatures from 293 K to 323 K allows obtaining important information about the texture and surface properties of these novel materials. Our results reveal how the interplay of confined geometry effects and the strength of the adsorption forces influences the sorption, wetting and phase behavior of simple fluids and water, which is of importance for an advanced textural characterization of micro- and mesoporous materials. We present an advanced study of the physical adsorption of pure fluids, such as argon and nitrogen, and water vapor, on novel micro/mesoporous zeolites Beta and ZSM-5 as well as on mesoporous molecular sieves (e.g. SBA-16). We demonstrate that combining the adsorption of nitrogen at 77.4 K and argon at 87.3 K with a systematic water vapor sorption study performed at temperatures from 293 K to 323 K allows obtaining important information about the texture and surface properties of these novel materials. Our results reveal how the interplay of confined geometry effects and the strength of the adsorption forces influences the sorption, wetting and phase behavior of simple fluids and water, which is of importance for an advanced textural characterization of micro- and mesoporous materials. V této studii je ukázána pokročilá studie fyzikální adsorpce čistých medií, jako argonu, dusíku a vodní páry, na mikro-mesoporézním zeolitu ZSM-5, jakož i na mesoporézních molekulových sítech (např., SBA-16). Kombinací adsorpce dusíku při 77.4 K a argonu při 87.3 K se systematickou studií sorpce vodní páry při teplotách 293 až 323 K umožňuje získat důležité informace o textuře a povrchových vlastnostech těchto moderních materiálů. Souhra vlivu omezené geometrie a adsorpčních sil ovlivňuje sorpční, smáčecí a fázové chování jednoduchých tekutin a vody, což má význam pro pokročilou texturní charakterizaci mikro a mesoporézních materiálů.
dcterms:title
Adsorpční vlastnosti a pokročilá texturní charakterizace moderních mikro-mesoporézních zeolitů Adsorption properties and advanced textural characterization of novel micro/mesoporous zeolites Adsorption properties and advanced textural characterization of novel micro/mesoporous zeolites
skos:prefLabel
Adsorption properties and advanced textural characterization of novel micro/mesoporous zeolites Adsorption properties and advanced textural characterization of novel micro/mesoporous zeolites Adsorpční vlastnosti a pokročilá texturní charakterizace moderních mikro-mesoporézních zeolitů
skos:notation
RIV/61388955:_____/07:00092692!RIV08-MSM-61388955
n4:strany
1042;1047
n4:aktivita
n16:P n16:Z
n4:aktivity
P(1M0577), Z(AV0Z40400503)
n4:dodaniDat
n6:2008
n4:domaciTvurceVysledku
n9:5120500
n4:druhVysledku
n12:C
n4:duvernostUdaju
n17:S
n4:entitaPredkladatele
n13:predkladatel
n4:idSjednocenehoVysledku
408632
n4:idVysledku
RIV/61388955:_____/07:00092692
n4:jazykVysledku
n5:eng
n4:klicovaSlova
micro/mesoporous zeolites; adsorption; textural characterization
n4:klicoveSlovo
n11:textural%20characterization n11:adsorption n11:micro%2Fmesoporous%20zeolites
n4:kontrolniKodProRIV
[FC5CC0FBC9DA]
n4:mistoVydani
Amsterdam
n4:nazevEdiceCisloSvazku
Studies in surface science and catalysis
n4:nazevZdroje
From Zeolites to Porous MOF Materials - the 40th Anniversary of International Zeolite Conference
n4:obor
n20:CF
n4:pocetDomacichTvurcuVysledku
1
n4:pocetTvurcuVysledku
2
n4:projekt
n7:1M0577
n4:rokUplatneniVysledku
n6:2007
n4:tvurceVysledku
Thommes, M. Rathouský, Jiří
n4:zamer
n15:AV0Z40400503
s:numberOfPages
6
n18:hasPublisher
Elsevier
n19:isbn
978-0-444-53068-4