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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F07%3A00091821%21RIV08-MSM-61388955
rdf:type
n6:Vysledek skos:Concept
dcterms:description
Rozšířili jsme měření radikálu FC16O2 do nižší frekvenční oblasti, mezi 210 až 245 GHz pomocí nedávno vyvinutého mikrovlnného spektrometru v Praze. Bylo pozorováno okolo 60 nových přechodů a-typu R větve. Naše současná analýza umožnila podstatně vylepšit určení konstant základního stavu. We have subsequently extended the measurement of the FC(16)O2 radical to the lower frequency region, between 210 and 245 GHz with the recently developed Prague microwave spectrometer. About 60 new a-type R-branch transitions have been observed. Our present analysis enabled us to improve significantly the determination of the ground state constants: most of the parameters are now determined with higher precision up to an order of magnitude better than the previous study. In addition eight new constants could be determined or nearly determinable for the first time. We have subsequently extended the measurement of the FC(16)O2 radical to the lower frequency region, between 210 and 245 GHz with the recently developed Prague microwave spectrometer. About 60 new a-type R-branch transitions have been observed. Our present analysis enabled us to improve significantly the determination of the ground state constants: most of the parameters are now determined with higher precision up to an order of magnitude better than the previous study. In addition eight new constants could be determined or nearly determinable for the first time.
dcterms:title
High resolution rotational spectrum of FCO2 radical (extension to lower frequencies) High resolution rotational spectrum of FCO2 radical (extension to lower frequencies) Vysoce rozlišené rotační spektrum radikálu FCO2 (rozšíření do nižších frekvencí)
skos:prefLabel
Vysoce rozlišené rotační spektrum radikálu FCO2 (rozšíření do nižších frekvencí) High resolution rotational spectrum of FCO2 radical (extension to lower frequencies) High resolution rotational spectrum of FCO2 radical (extension to lower frequencies)
skos:notation
RIV/61388955:_____/07:00091821!RIV08-MSM-61388955
n3:strany
292;295
n3:aktivita
n9:Z n9:P
n3:aktivity
P(1ET400400410), P(GA202/06/0216), P(IAA400400504), P(LC06071), Z(AV0Z40400503), Z(MSM6046137307)
n3:cisloPeriodika
2
n3:dodaniDat
n4:2008
n3:domaciTvurceVysledku
n8:1011790 n8:2917114 n8:8863105 n8:5814804 n8:9913343
n3:druhVysledku
n17:J
n3:duvernostUdaju
n10:S
n3:entitaPredkladatele
n11:predkladatel
n3:idSjednocenehoVysledku
424093
n3:idVysledku
RIV/61388955:_____/07:00091821
n3:jazykVysledku
n16:eng
n3:klicovaSlova
fluoroformyloxyl radical; milimeter wave spectroscopy; ground vibrational state; Pickett analysis
n3:klicoveSlovo
n7:Pickett%20analysis n7:ground%20vibrational%20state n7:milimeter%20wave%20spectroscopy n7:fluoroformyloxyl%20radical
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[2BE2C1EAB121]
n3:nazevZdroje
Journal of Molecular Spectroscopy
n3:obor
n12:CF
n3:pocetDomacichTvurcuVysledku
5
n3:pocetTvurcuVysledku
11
n3:projekt
n15:GA202%2F06%2F0216 n15:IAA400400504 n15:1ET400400410 n15:LC06071
n3:rokUplatneniVysledku
n4:2007
n3:svazekPeriodika
243
n3:tvurceVysledku
Kolesníková, L. Šimečková, Marie Willner, H. Beckers, H. Stříteská, L. Bailleux, S. Zelinger, Zdeněk Kania, Patrik Musil, P. Babánková, Dagmar Urban, Štěpán
n3:zamer
n18:AV0Z40400503 n18:MSM6046137307
s:issn
0022-2852
s:numberOfPages
4