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Subject Item
n2:RIV%2F61388955%3A_____%2F07%3A00085408%21RIV08-MSM-61388955
rdf:type
skos:Concept n12:Vysledek
dcterms:description
The mononuclear complexes [(eta(5)-C5Me5)IrCl(L-1)] (1), [(eta(5)-C5Me5)RhCl(L-1)] (2), [(eta(6)-p-Pr´C6H4Me)RuCl(L-1)] (3) and [(eta(6)- C6Me6)RuCl(L-1)] (4) have been synthesised from pyrazine-2-carboxylic acid (HL1) and the corresponding complexes [{(eta(5)- C5Me5)IrCl2)(2)], [{(eta(5)-C5Me5)RhCl2)(2)], [{(eta(6)-p-Pr´C6H4Me)RuCl2}(2)], and [{(eta(6)-C6Me6)RuCl2}(2)], respectively. The related dinuclear complexes [{(eta(5)-C5Me5)IrCl)(2)(mu-L-2)] (5), [{(eta(5)-C5Me5)RhCl}(2)(mu-L-2)] (6), [{(n(6)-p-(PrC6H4Me)-C-i)RuCl}(2)(mu-L-2)] (7) and [(eta(6)-C6Me6)R-uCl} (2)(mu-L-2)] (8) have been obtained in a similar manner from pyrazine-2,5-dicarboxylic acid (H2L2). Compounds isomeric to the latter series, [{(eta(5)-C5Me5)IrCl}(2)(mu-L-3)] (9), [{(eta(5)-C5Me5)RhCl}(2)(mu-L-3)] (10), [{(p-Pr´C6H4Me)RuCl}(2)(mu-L-3)] (11) and [{(eta(6)-C6Me6)RuCl}(2)(mu-L-3 )] (12), have been prepared by using pyrazine-2,3-dicarboxylic acid (H2L3) instead of H2L2. Ve vodě rozpustné jedno- a dvojjaderné Ir, Rh a Ru komplexy obsahující současně „měkké“ chelátující organické a „tvrdé“ hydrofilní ligandy jsou slibnými hydrogenačními katalyzátory díky své schopnosti pH-selektivně koordinovat vodu. Elektrochemické studium oxidace i redukce serií těchto sloučenin, které obsahují bipyrimidinové ligandy umožnilo charakterizovat jejich redox vlastnosti a intramolekulární elektronické interakce a korelovat je s katalytickou aktivitou. The mononuclear complexes [(eta(5)-C5Me5)IrCl(L-1)] (1), [(eta(5)-C5Me5)RhCl(L-1)] (2), [(eta(6)-p-Pr´C6H4Me)RuCl(L-1)] (3) and [(eta(6)- C6Me6)RuCl(L-1)] (4) have been synthesised from pyrazine-2-carboxylic acid (HL1) and the corresponding complexes [{(eta(5)- C5Me5)IrCl2)(2)], [{(eta(5)-C5Me5)RhCl2)(2)], [{(eta(6)-p-Pr´C6H4Me)RuCl2}(2)], and [{(eta(6)-C6Me6)RuCl2}(2)], respectively. The related dinuclear complexes [{(eta(5)-C5Me5)IrCl)(2)(mu-L-2)] (5), [{(eta(5)-C5Me5)RhCl}(2)(mu-L-2)] (6), [{(n(6)-p-(PrC6H4Me)-C-i)RuCl}(2)(mu-L-2)] (7) and [(eta(6)-C6Me6)R-uCl} (2)(mu-L-2)] (8) have been obtained in a similar manner from pyrazine-2,5-dicarboxylic acid (H2L2). Compounds isomeric to the latter series, [{(eta(5)-C5Me5)IrCl}(2)(mu-L-3)] (9), [{(eta(5)-C5Me5)RhCl}(2)(mu-L-3)] (10), [{(p-Pr´C6H4Me)RuCl}(2)(mu-L-3)] (11) and [{(eta(6)-C6Me6)RuCl}(2)(mu-L-3 )] (12), have been prepared by using pyrazine-2,3-dicarboxylic acid (H2L3) instead of H2L2.
dcterms:title
Jedno a dvoujaderné komplexy rhodia, iridia a ruthenia obsahujíci karboxylátové pyrazinové ligandy: Syntéza, molekulová struktura, elektrochemie a katalytické vlastnosti Mono and dinuclear iridium, rhodium and ruthenium complexes containing chelating carboxylato pyrazine ligands: Synthesis, molecular structure and electrochemistry Mono and dinuclear iridium, rhodium and ruthenium complexes containing chelating carboxylato pyrazine ligands: Synthesis, molecular structure and electrochemistry
skos:prefLabel
Mono and dinuclear iridium, rhodium and ruthenium complexes containing chelating carboxylato pyrazine ligands: Synthesis, molecular structure and electrochemistry Mono and dinuclear iridium, rhodium and ruthenium complexes containing chelating carboxylato pyrazine ligands: Synthesis, molecular structure and electrochemistry Jedno a dvoujaderné komplexy rhodia, iridia a ruthenia obsahujíci karboxylátové pyrazinové ligandy: Syntéza, molekulová struktura, elektrochemie a katalytické vlastnosti
skos:notation
RIV/61388955:_____/07:00085408!RIV08-MSM-61388955
n4:strany
1661;1671
n4:aktivita
n13:P n13:Z
n4:aktivity
P(LC06070), P(LC510), Z(AV0Z40400503), Z(MSM0021620857)
n4:cisloPeriodika
8
n4:dodaniDat
n18:2008
n4:domaciTvurceVysledku
n10:4441613
n4:druhVysledku
n9:J
n4:duvernostUdaju
n16:S
n4:entitaPredkladatele
n11:predkladatel
n4:idSjednocenehoVysledku
435016
n4:idVysledku
RIV/61388955:_____/07:00085408
n4:jazykVysledku
n8:eng
n4:klicovaSlova
dinuclear complexes; iridium; rhodium; ruthenium; electrochemistry
n4:klicoveSlovo
n7:dinuclear%20complexes n7:electrochemistry n7:iridium n7:ruthenium n7:rhodium
n4:kodStatuVydavatele
CH - Švýcarská konfederace
n4:kontrolniKodProRIV
[49747A2B6DC2]
n4:nazevZdroje
Journal of Organometallic Chemistry
n4:obor
n17:CG
n4:pocetDomacichTvurcuVysledku
1
n4:pocetTvurcuVysledku
5
n4:projekt
n5:LC06070 n5:LC510
n4:rokUplatneniVysledku
n18:2007
n4:svazekPeriodika
692
n4:tvurceVysledku
Štěpnička, P. Süss-Fink, G. Therrien, B. Govindaswamy, P. Ludvík, Jiří
n4:zamer
n15:MSM0021620857 n15:AV0Z40400503
s:issn
0022-328X
s:numberOfPages
11