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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F06%3A00035887%21RIV07-AV0-61388955
rdf:type
skos:Concept n14:Vysledek
dcterms:description
Under light irradiation at 313 nm with a medium-pressure mercury lamp, a gaseous mixture of trimethyl(2-propynyloxy)silane (TMPSi) and carbon disulfide (CS2) produced sedimentary aerosol particles. From measurement of monitor (He-Ne laser) light intensity scattered by the aerosol particles, it was shown that the nucleation process of the aerosol particles was accelerated with increasing partial pressure of TMPSi. Analysis of FT-IR and X-ray photoelectron spectra (XPS) of the sedimentary aerosol particles revealed that excited CS, molecules reacted with TMPSi at C equivalent to C to initiate nucleation reaction of the particle formation. Several chemical species originated from CS2 were incorporated into the polymerization reactions between TMPSi and CS2 in forming > C=S and C-S chemical bonds. Under light irradiation at 313 nm with a medium-pressure mercury lamp, a gaseous mixture of trimethyl(2-propynyloxy)silane (TMPSi) and carbon disulfide (CS2) produced sedimentary aerosol particles. From measurement of monitor (He-Ne laser) light intensity scattered by the aerosol particles, it was shown that the nucleation process of the aerosol particles was accelerated with increasing partial pressure of TMPSi. Analysis of FT-IR and X-ray photoelectron spectra (XPS) of the sedimentary aerosol particles revealed that excited CS, molecules reacted with TMPSi at C equivalent to C to initiate nucleation reaction of the particle formation. Several chemical species originated from CS2 were incorporated into the polymerization reactions between TMPSi and CS2 in forming > C=S and C-S chemical bonds. Působením UV záření o vlnové délce 313 nm na plynnou směs trimethyl(2-propynyloxy)silanu (TMPSi) a sirouhlíku vznikají aerosolové částice. Z měření rozptylu záření He-Ne laseru vyplynulo, že nukleační process je urychlen růstem parciálního tlaku TMPSi. Analýza částic aerosolu metodami FTIR a XPS, že excitované molekuly sirouhlíku reagují s C=C vazbou TMPSi a iniciují nukleaci částic.
dcterms:title
Photochemical synthesis of ultrafine organosilicon particles from trimethyl(2-propynyloxy)silane and carbon disulfide Fotochemická syntéza ultračistých organosilikonových částic z trimethyl(2-propynyloxy)silanu a CO2 Photochemical synthesis of ultrafine organosilicon particles from trimethyl(2-propynyloxy)silane and carbon disulfide
skos:prefLabel
Photochemical synthesis of ultrafine organosilicon particles from trimethyl(2-propynyloxy)silane and carbon disulfide Fotochemická syntéza ultračistých organosilikonových částic z trimethyl(2-propynyloxy)silanu a CO2 Photochemical synthesis of ultrafine organosilicon particles from trimethyl(2-propynyloxy)silane and carbon disulfide
skos:notation
RIV/61388955:_____/06:00035887!RIV07-AV0-61388955
n3:strany
142;148
n3:aktivita
n15:Z
n3:aktivity
Z(AV0Z40320502), Z(AV0Z40400503), Z(AV0Z40720504)
n3:cisloPeriodika
1-2
n3:dodaniDat
n12:2007
n3:domaciTvurceVysledku
n17:7579543
n3:druhVysledku
n16:J
n3:duvernostUdaju
n13:S
n3:entitaPredkladatele
n8:predkladatel
n3:idSjednocenehoVysledku
492003
n3:idVysledku
RIV/61388955:_____/06:00035887
n3:jazykVysledku
n6:eng
n3:klicovaSlova
ultrafine particles; photo-polymerization; trimethyl(2-propynyloxy)silane; carbon disulfide
n3:klicoveSlovo
n11:photo-polymerization n11:trimethyl%282-propynyloxy%29silane n11:ultrafine%20particles n11:carbon%20disulfide
n3:kodStatuVydavatele
CH - Švýcarská konfederace
n3:kontrolniKodProRIV
[D5818BE39DE7]
n3:nazevZdroje
Journal of Photochemistry and Photobiology. A - Chemistry Section
n3:obor
n9:CF
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
5
n3:rokUplatneniVysledku
n12:2006
n3:svazekPeriodika
179
n3:tvurceVysledku
Morita, H. Bastl, Zdeněk Nozawa, R. Šubrt, Jan Pola, Josef
n3:zamer
n10:AV0Z40320502 n10:AV0Z40400503 n10:AV0Z40720504
s:issn
1010-6030
s:numberOfPages
7