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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F05%3A00023193%21RIV06-AV0-61388955
rdf:type
skos:Concept n18:Vysledek
dcterms:description
Sloučenina [(dppp)(AuCl)2], která může asociovat intermolekulárně v řetězové (catena) struktuře AuI -AuI interakcí (3.316 A), byla připravena z Au(III) prekursoru v cyclo formě s intramolekulárním AuI -AuI kontaktem 3.237 Å a AuPCCCPAu sedmi-členným kruhem. DFT výpočty používající velké relativistické báze reprodukovaly d10-d10 interakci a popsaly pozorovanou molekulární strukturu v krystalu včetně výrazné distorse jednoho ze zlatých atomů. Chelátový komplex [(dppp)PtCl2] byl krystalizován a strukturně charakterizován. The compound [(mu-dppp)(AuCl)2], previously reported to associate intermolecularly in a chain (catena) structure through AuI -AuI interactions (3.316 angstrom), was obtained from gold(III) precursors in a cyclo form with shortened intramolecular AuI -AuI contacts at 3.237 angstrom and a puckered AuPCCCPAu seven-membered ring. DFT calculations using a large relativistic basis to account for the d10-d10) interaction reproduce the observed molecular structure in the crystal of this %22linkage isomer%22, including the conspicuous distortion at one of the gold atoms. The chelate complex [(dppp)PtCl2] was crystallized and structurally characterized as the dichloromethane solvate. The compound [(mu-dppp)(AuCl)2], previously reported to associate intermolecularly in a chain (catena) structure through AuI -AuI interactions (3.316 angstrom), was obtained from gold(III) precursors in a cyclo form with shortened intramolecular AuI -AuI contacts at 3.237 angstrom and a puckered AuPCCCPAu seven-membered ring. DFT calculations using a large relativistic basis to account for the d10-d10) interaction reproduce the observed molecular structure in the crystal of this %22linkage isomer%22, including the conspicuous distortion at one of the gold atoms. The chelate complex [(dppp)PtCl2] was crystallized and structurally characterized as the dichloromethane solvate.
dcterms:title
Complexes of 1,3-Bis(diphenylphosphano)propane (dppp) with Dichloroplatinum(II) and Bis(chlorogold(I)): Intramolecular versus Intermolecular AuI -AuI Association of [(.mu.-dppp)(AuCl)2] in catena and cyclo Forms Komplexy 1,3-Bis(difenylfosfan)propanu (dppp) s dichloroplatinou(II) a bis(chlorozlatem(I)): intramolekulární versus intermolekulární AuI -AuI asociace [(.mu.-dppp)(AuCl)2] v catena a cyclo formách Complexes of 1,3-Bis(diphenylphosphano)propane (dppp) with Dichloroplatinum(II) and Bis(chlorogold(I)): Intramolecular versus Intermolecular AuI -AuI Association of [(.mu.-dppp)(AuCl)2] in catena and cyclo Forms
skos:prefLabel
Complexes of 1,3-Bis(diphenylphosphano)propane (dppp) with Dichloroplatinum(II) and Bis(chlorogold(I)): Intramolecular versus Intermolecular AuI -AuI Association of [(.mu.-dppp)(AuCl)2] in catena and cyclo Forms Complexes of 1,3-Bis(diphenylphosphano)propane (dppp) with Dichloroplatinum(II) and Bis(chlorogold(I)): Intramolecular versus Intermolecular AuI -AuI Association of [(.mu.-dppp)(AuCl)2] in catena and cyclo Forms Komplexy 1,3-Bis(difenylfosfan)propanu (dppp) s dichloroplatinou(II) a bis(chlorozlatem(I)): intramolekulární versus intermolekulární AuI -AuI asociace [(.mu.-dppp)(AuCl)2] v catena a cyclo formách
skos:notation
RIV/61388955:_____/05:00023193!RIV06-AV0-61388955
n5:strany
1355;1358
n5:aktivita
n9:P n9:Z
n5:aktivity
P(1ET400400413), P(1P04OCD14.20), Z(AV0Z40400503)
n5:cisloPeriodika
8
n5:dodaniDat
n10:2006
n5:domaciTvurceVysledku
n14:3953084
n5:druhVysledku
n11:J
n5:duvernostUdaju
n13:S
n5:entitaPredkladatele
n7:predkladatel
n5:idSjednocenehoVysledku
516012
n5:idVysledku
RIV/61388955:_____/05:00023193
n5:jazykVysledku
n16:eng
n5:klicovaSlova
gold; platinum; d(10)-d(10) interaction; diphosphane ligand
n5:klicoveSlovo
n6:gold n6:diphosphane%20ligand n6:platinum n6:d%2810%29-d%2810%29%20interaction
n5:kodStatuVydavatele
DE - Spolková republika Německo
n5:kontrolniKodProRIV
[56941E258040]
n5:nazevZdroje
Zeitschrift für anorganische und allgemeine Chemie
n5:obor
n15:CG
n5:pocetDomacichTvurcuVysledku
1
n5:pocetTvurcuVysledku
4
n5:projekt
n8:1ET400400413 n8:1P04OCD14.20
n5:rokUplatneniVysledku
n10:2005
n5:svazekPeriodika
631
n5:tvurceVysledku
Dogan, A. Kaim, W. Klein, A. Záliš, Stanislav
n5:zamer
n17:AV0Z40400503
s:issn
0044-2313
s:numberOfPages
4