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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F05%3A00000711%21RIV11-GA0-61388955
rdf:type
n14:Vysledek skos:Concept
dcterms:description
New type of heterogeneous catalysts based on mesoporous molecular sieve MCM-41 modified with molybdenum oxide was proposed for the application in metathesis of linear 1-olefins. This catalyst prepared via %22thermal spreading method%22 operates in a liquid phase under ambient or slightly higher reaction temperature without the presence of solvent. The optimum loading of molybdenum oxide was 8 wt. % of Mo. For 1-octene, the conversion achieved in 390 min. at 40 oC was 74 %, and the selectivity to 14-tetradecene was 82 %. New type of heterogeneous catalysts based on mesoporous molecular sieve MCM-41 modified with molybdenum oxide was proposed for the application in metathesis of linear 1-olefins. This catalyst prepared via %22thermal spreading method%22 operates in a liquid phase under ambient or slightly higher reaction temperature without the presence of solvent. The optimum loading of molybdenum oxide was 8 wt. % of Mo. For 1-octene, the conversion achieved in 390 min. at 40 oC was 74 %, and the selectivity to 14-tetradecene was 82 %.
dcterms:title
Metathesis of linear .alpha.-olefins with MoO3 supported on MCM-41 catalyst Metathesis of linear .alpha.-olefins with MoO3 supported on MCM-41 catalyst
skos:prefLabel
Metathesis of linear .alpha.-olefins with MoO3 supported on MCM-41 catalyst Metathesis of linear .alpha.-olefins with MoO3 supported on MCM-41 catalyst
skos:notation
RIV/61388955:_____/05:00000711!RIV11-GA0-61388955
n3:aktivita
n7:P n7:Z
n3:aktivity
P(GD203/03/H140), P(IAA4040411), Z(AV0Z40400503)
n3:dodaniDat
n9:2011
n3:domaciTvurceVysledku
n12:7016662 n12:6503284 n12:3040291 n12:4766350
n3:druhVysledku
n18:D
n3:duvernostUdaju
n11:S
n3:entitaPredkladatele
n13:predkladatel
n3:idSjednocenehoVysledku
529686
n3:idVysledku
RIV/61388955:_____/05:00000711
n3:jazykVysledku
n17:eng
n3:klicovaSlova
heterogeneous catalyst; X-ray diffraction; catalytic reaction
n3:klicoveSlovo
n4:X-ray%20diffraction n4:heterogeneous%20catalyst n4:catalytic%20reaction
n3:kontrolniKodProRIV
[8CC4326973D9]
n3:mistoKonaniAkce
Niagara Falls
n3:mistoVydani
Amsterdam
n3:nazevZdroje
Nanoporous Materials
n3:obor
n19:CF
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
5
n3:projekt
n15:GD203%2F03%2FH140 n15:IAA4040411
n3:rokUplatneniVysledku
n9:2005
n3:tvurceVysledku
Žilková, Naděžda Topka, Pavel Pérez-Pariente, J. Čejka, Jiří Balcar, Hynek
n3:typAkce
n8:WRD
n3:zahajeniAkce
2005-06-07+02:00
n3:zamer
n16:AV0Z40400503
s:numberOfPages
8
n21:hasPublisher
Elsevier
n6:isbn
978-0-444-51748-7