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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F03%3A54030162%21RIV%2F2004%2FAV0%2FA54004%2FN
rdf:type
skos:Concept n15:Vysledek
dcterms:description
Dissociations and reactions induced by impact of acetonitrile monomer ions (CH3CN+, CD3CN+), dimer ions [(CH3CN)(2)(+), (CD3CN)(2)(+)] and trimer ions [(CD3CN)(3)(+)] on a hydrocarbon-covered stainless-steel surface were investigated over the projectile energy range of 3-70 eV. Both simple dissociations of the projectile ion and chemical reactions of H-atom transfer from the surface material (followed by dissociations of the protonated projectile ion formed) were observed for the monomer ions. Results obtained for the dimer ions (CD3CN)(2)(+) indicate the formation of the protonated acetonitrile ions via surface-induced reactions in two ways: (i) an intracluster ion-molecule reaction followed by dissociation to form CD3CND+, and (b) a hydrogen pick-up reaction from the surface material during the interaction of the dimer ion with the surface leading to CD3CNH+. A simple model based on the Brauman double-well potential-suggested earlier to explain the occurrence. Dissociations and reactions induced by impact of acetonitrile monomer ions (CH3CN+, CD3CN+), dimer ions [(CH3CN)(2)(+), (CD3CN)(2)(+)] and trimer ions [(CD3CN)(3)(+)] on a hydrocarbon-covered stainless-steel surface were investigated over the projectile energy range of 3-70 eV. Both simple dissociations of the projectile ion and chemical reactions of H-atom transfer from the surface material (followed by dissociations of the protonated projectile ion formed) were observed for the monomer ions. Results obtained for the dimer ions (CD3CN)(2)(+) indicate the formation of the protonated acetonitrile ions via surface-induced reactions in two ways: (i) an intracluster ion-molecule reaction followed by dissociation to form CD3CND+, and (b) a hydrogen pick-up reaction from the surface material during the interaction of the dimer ion with the surface leading to CD3CNH+. A simple model based on the Brauman double-well potential-suggested earlier to explain the occurrence.
dcterms:title
Surface Induced Dissociations and Reactions of Acetonitrile Monomer, Dimer and Trimer Ions. Surface Induced Dissociations and Reactions of Acetonitrile Monomer, Dimer and Trimer Ions.
skos:prefLabel
Surface Induced Dissociations and Reactions of Acetonitrile Monomer, Dimer and Trimer Ions. Surface Induced Dissociations and Reactions of Acetonitrile Monomer, Dimer and Trimer Ions.
skos:notation
RIV/61388955:_____/03:54030162!RIV/2004/AV0/A54004/N
n3:strany
1479;1486
n3:aktivita
n11:Z n11:P
n3:aktivity
P(GA203/00/0632), Z(AV0Z4040901)
n3:cisloPeriodika
3
n3:dodaniDat
n8:2004
n3:domaciTvurceVysledku
n14:1023039
n3:druhVysledku
n17:J
n3:duvernostUdaju
n13:S
n3:entitaPredkladatele
n18:predkladatel
n3:idSjednocenehoVysledku
629784
n3:idVysledku
RIV/61388955:_____/03:54030162
n3:jazykVysledku
n4:eng
n3:klicovaSlova
surface-induced; acetonitrile monomer; trimer ions
n3:klicoveSlovo
n9:trimer%20ions n9:acetonitrile%20monomer n9:surface-induced
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[A6C404C8E4FB]
n3:nazevZdroje
Journal of Chemical Physics
n3:obor
n12:CF
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
5
n3:pocetUcastnikuAkce
0
n3:pocetZahranicnichUcastnikuAkce
0
n3:projekt
n10:GA203%2F00%2F0632
n3:rokUplatneniVysledku
n8:2003
n3:svazekPeriodika
118
n3:tvurceVysledku
Fedor, J. Mair, C. Lezius, M. Märk, T. D. Herman, Zdeněk
n3:zamer
n16:AV0Z4040901
s:issn
0021-9606
s:numberOfPages
8