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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F03%3A54030155%21RIV%2F2004%2FAV0%2FA54004%2FN
rdf:type
n11:Vysledek skos:Concept
dcterms:description
Thermally programmed desorption technique has been applied to the investigation of 'virgin' and repeated adsorption of carbon monoxide on Pd/Nb and Pd/Nb2O5/Nb systems. The desorbed products of the CO interaction with these surfaces, namely, CO and CO2 molecules were monitored by a quadrupole mass spectrometer. On the basis of presented results some of the observed differences between the metal- and oxide-supported active metal (Pd) have been ascribed to the morphological rather than to chemical (electronic) effects in these systems. The different excess kinetic energy dissipation of Pd atoms colliding with metallic or oxidic surface is considered to influence the initial growth of the Pd layer, resulting afterwards in a different morphology of the final Pd layers. Thermally programmed desorption technique has been applied to the investigation of 'virgin' and repeated adsorption of carbon monoxide on Pd/Nb and Pd/Nb2O5/Nb systems. The desorbed products of the CO interaction with these surfaces, namely, CO and CO2 molecules were monitored by a quadrupole mass spectrometer. On the basis of presented results some of the observed differences between the metal- and oxide-supported active metal (Pd) have been ascribed to the morphological rather than to chemical (electronic) effects in these systems. The different excess kinetic energy dissipation of Pd atoms colliding with metallic or oxidic surface is considered to influence the initial growth of the Pd layer, resulting afterwards in a different morphology of the final Pd layers.
dcterms:title
Carbon Monoxide Chemisorption and Disproportionation on Thin Palladium Layers, Supported by Niobium and Niobium Pentoxide. Carbon Monoxide Chemisorption and Disproportionation on Thin Palladium Layers, Supported by Niobium and Niobium Pentoxide.
skos:prefLabel
Carbon Monoxide Chemisorption and Disproportionation on Thin Palladium Layers, Supported by Niobium and Niobium Pentoxide. Carbon Monoxide Chemisorption and Disproportionation on Thin Palladium Layers, Supported by Niobium and Niobium Pentoxide.
skos:notation
RIV/61388955:_____/03:54030155!RIV/2004/AV0/A54004/N
n3:strany
1833;1847
n3:aktivita
n6:P n6:Z
n3:aktivity
P(GA202/02/0618), P(GV202/98/K002), Z(AV0Z4040901)
n3:cisloPeriodika
10
n3:dodaniDat
n4:2004
n3:domaciTvurceVysledku
n7:4198433 Thiam, Michel Malick n7:4576209 n7:3731960
n3:druhVysledku
n8:J
n3:duvernostUdaju
n12:S
n3:entitaPredkladatele
n17:predkladatel
n3:idSjednocenehoVysledku
600351
n3:idVysledku
RIV/61388955:_____/03:54030155
n3:jazykVysledku
n18:eng
n3:klicovaSlova
thermally programmed desorption; energy dissipation; carbon monoxide
n3:klicoveSlovo
n13:thermally%20programmed%20desorption n13:energy%20dissipation n13:carbon%20monoxide
n3:kodStatuVydavatele
CZ - Česká republika
n3:kontrolniKodProRIV
[C4D3DE195D4B]
n3:nazevZdroje
Collection of Czechoslovak Chemical Communications
n3:obor
n10:CF
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
4
n3:pocetUcastnikuAkce
0
n3:pocetZahranicnichUcastnikuAkce
0
n3:projekt
n16:GV202%2F98%2FK002 n16:GA202%2F02%2F0618
n3:rokUplatneniVysledku
n4:2003
n3:svazekPeriodika
68
n3:tvurceVysledku
Nikolajenko, Vladimír Thiam, Michel Malick Knor, Zlatko Plšek, Jan
n3:zamer
n14:AV0Z4040901
s:issn
0010-0765
s:numberOfPages
15