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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F03%3A54030106%21RIV%2F2004%2FAV0%2FA54004%2FN
rdf:type
n12:Vysledek skos:Concept
dcterms:description
Photodissociation experiments are carried out for single HBr molecules which areembedded in the interior or absorbed on the surface of large Ar$_n$ clusters.For the embedded case the size dependence is measured for the average sizesn=51, 139, 230, 290, and 450. For the surface case and the average sizen=139 the cluster temperature is varied by changing the source temperature fromT=163 K to 263 K. The measured kinetic energy of the H atom fragments is measuredexhibiting peaks at zero and 1.3 eV which mark completely caged and unperturbedfragments, respectively. The results are compared with Molecular Dynamics simulationswhich account for the quantum librational delocalization of the HBr molecule. The location of the molecule in/on the cluster is obtained from a trajectory study of the pick-upprocess under realistic conditions. For the embedded case corresponding to aco-expansion experiment, three argon layers are sufficient to completely hinderthe H atom. Photodissociation experiments are carried out for single HBr molecules which areembedded in the interior or absorbed on the surface of large Ar$_n$ clusters.For the embedded case the size dependence is measured for the average sizesn=51, 139, 230, 290, and 450. For the surface case and the average sizen=139 the cluster temperature is varied by changing the source temperature fromT=163 K to 263 K. The measured kinetic energy of the H atom fragments is measuredexhibiting peaks at zero and 1.3 eV which mark completely caged and unperturbedfragments, respectively. The results are compared with Molecular Dynamics simulationswhich account for the quantum librational delocalization of the HBr molecule. The location of the molecule in/on the cluster is obtained from a trajectory study of the pick-upprocess under realistic conditions. For the embedded case corresponding to aco-expansion experiment, three argon layers are sufficient to completely hinderthe H atom.
dcterms:title
Photodissociation of HBr in and on Arn Clusters: The Role of the Position of the Molecule. Photodissociation of HBr in and on Arn Clusters: The Role of the Position of the Molecule.
skos:prefLabel
Photodissociation of HBr in and on Arn Clusters: The Role of the Position of the Molecule. Photodissociation of HBr in and on Arn Clusters: The Role of the Position of the Molecule.
skos:notation
RIV/61388955:_____/03:54030106!RIV/2004/AV0/A54004/N
n3:strany
3394;3401
n3:aktivita
n16:Z n16:P
n3:aktivity
P(LN00A032), Z(AV0Z4040901)
n3:cisloPeriodika
N/A
n3:dodaniDat
n9:2004
n3:domaciTvurceVysledku
n7:1781073 n7:2793911
n3:druhVysledku
n18:J
n3:duvernostUdaju
n15:S
n3:entitaPredkladatele
n14:predkladatel
n3:idSjednocenehoVysledku
620824
n3:idVysledku
RIV/61388955:_____/03:54030106
n3:jazykVysledku
n17:eng
n3:klicovaSlova
HBr; photodissociation; Arn clusters
n3:klicoveSlovo
n6:photodissociation n6:Arn%20clusters n6:HBr
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[CE4C42D13475]
n3:nazevZdroje
Physical Chemistry Chemical Physics
n3:obor
n13:CF
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
6
n3:pocetUcastnikuAkce
0
n3:pocetZahranicnichUcastnikuAkce
0
n3:projekt
n10:LN00A032
n3:rokUplatneniVysledku
n9:2003
n3:svazekPeriodika
5
n3:tvurceVysledku
Nahler, N. H. Buck, U. Jungwirth, Pavel Vach, H. Baumfalk, R. Slavíček, Petr
n3:zamer
n8:AV0Z4040901
s:issn
1463-9076
s:numberOfPages
8