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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F03%3A54030001%21RIV%2F2004%2FAV0%2FA54004%2FN
rdf:type
skos:Concept n15:Vysledek
dcterms:description
Thermodynamic analysis of the polarised interface between two immiscible electrolyte solutions (ITIES) was outlined, which accounts for the adsorption of phosphatidylcholine (PC) both as a zwitterion and a cation formed by the aqueous cation association with the zwitterionic PC form, as well as for the aqueous cation transfer facilitated by PC leading to its depletion from the interface. Electrocapillary equation was derived clarifying the physical significance of the surface charge density; the differential capacity and the PC surface excess concentration. The potential dependence of the interfacial tension calculated using the Damaskins adsorption model of a compound adsorbed in two different forms was found to agree well with that measured for the polarised water |1,2-dichloroethane interface in the presence of DL-alpha-dipalmitoylphosphatidylcholine. Experimentally observed effect of the nature of the aqueous cation on the interfacial tension was ascribed to the difference. Thermodynamic analysis of the polarised interface between two immiscible electrolyte solutions (ITIES) was outlined, which accounts for the adsorption of phosphatidylcholine (PC) both as a zwitterion and a cation formed by the aqueous cation association with the zwitterionic PC form, as well as for the aqueous cation transfer facilitated by PC leading to its depletion from the interface. Electrocapillary equation was derived clarifying the physical significance of the surface charge density; the differential capacity and the PC surface excess concentration. The potential dependence of the interfacial tension calculated using the Damaskins adsorption model of a compound adsorbed in two different forms was found to agree well with that measured for the polarised water |1,2-dichloroethane interface in the presence of DL-alpha-dipalmitoylphosphatidylcholine. Experimentally observed effect of the nature of the aqueous cation on the interfacial tension was ascribed to the difference.
dcterms:title
Thermodynamic Analysis of the Cation Binding to a Phosphatidylcholine Monolayer at a Polarised Interface between Two Immiscible Electrolyte Solutions. Thermodynamic Analysis of the Cation Binding to a Phosphatidylcholine Monolayer at a Polarised Interface between Two Immiscible Electrolyte Solutions.
skos:prefLabel
Thermodynamic Analysis of the Cation Binding to a Phosphatidylcholine Monolayer at a Polarised Interface between Two Immiscible Electrolyte Solutions. Thermodynamic Analysis of the Cation Binding to a Phosphatidylcholine Monolayer at a Polarised Interface between Two Immiscible Electrolyte Solutions.
skos:notation
RIV/61388955:_____/03:54030001!RIV/2004/AV0/A54004/N
n3:strany
98;103
n3:aktivita
n12:Z n12:P
n3:aktivity
P(GA203/01/0946), Z(AV0Z4040901)
n3:cisloPeriodika
1
n3:dodaniDat
n11:2004
n3:domaciTvurceVysledku
n6:2681544 n6:1415840
n3:druhVysledku
n7:J
n3:duvernostUdaju
n10:S
n3:entitaPredkladatele
n9:predkladatel
n3:idSjednocenehoVysledku
630929
n3:idVysledku
RIV/61388955:_____/03:54030001
n3:jazykVysledku
n17:eng
n3:klicovaSlova
ITIES; phosphatidylcholine; adsorption
n3:klicoveSlovo
n4:ITIES n4:adsorption n4:phosphatidylcholine
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[926F8A2FF1CE]
n3:nazevZdroje
Electrochemistry Communications
n3:obor
n16:CG
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
3
n3:pocetUcastnikuAkce
0
n3:pocetZahranicnichUcastnikuAkce
0
n3:projekt
n18:GA203%2F01%2F0946
n3:rokUplatneniVysledku
n11:2003
n3:svazekPeriodika
5
n3:tvurceVysledku
Girault, H. H. Trojánek, Antonín Samec, Zdeněk
n3:zamer
n14:AV0Z4040901
s:issn
1388-2481
s:numberOfPages
6