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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F02%3A54020193%21RIV%2F2003%2FAV0%2FA54003%2FN
rdf:type
skos:Concept n15:Vysledek
dcterms:description
The new complexes (RN=CH-CH=NR)Co(NO)(CO), R = isopropyl (1), 2,6-diisopropylphenyl (2) and p-tolyl (3), were synthesized and spectroscopically characterized. Compounds I and 2 could be crystallized for X-ray structure analysis, CO/NO disorder was observed for 1. The results indicate a negligible amount of charge transfer from the Co(NO)(CO) moiety to the 1,4-diaza-butadiene acceptor ligands in the ground state, in agreement with DFT calculations on I and as similarly reported for related 1,4-diaza-1,3-butadiene complexes of Ni(CO)(2) and Fe(NO)(2). The new complexes (RN=CH-CH=NR)Co(NO)(CO), R = isopropyl (1), 2,6-diisopropylphenyl (2) and p-tolyl (3), were synthesized and spectroscopically characterized. Compounds I and 2 could be crystallized for X-ray structure analysis, CO/NO disorder was observed for 1. The results indicate a negligible amount of charge transfer from the Co(NO)(CO) moiety to the 1,4-diaza-butadiene acceptor ligands in the ground state, in agreement with DFT calculations on I and as similarly reported for related 1,4-diaza-1,3-butadiene complexes of Ni(CO)(2) and Fe(NO)(2).
dcterms:title
Geometrical and ground state electronic structures of nitrosylcobalt complexes [(RNCHCHNR)Co(NO)(CO)] (R = isopropyl, 2,6-diisopropylphenyl or p-tolyl) from experiment and DFT-calculations. Geometrical and ground state electronic structures of nitrosylcobalt complexes [(RNCHCHNR)Co(NO)(CO)] (R = isopropyl, 2,6-diisopropylphenyl or p-tolyl) from experiment and DFT-calculations.
skos:prefLabel
Geometrical and ground state electronic structures of nitrosylcobalt complexes [(RNCHCHNR)Co(NO)(CO)] (R = isopropyl, 2,6-diisopropylphenyl or p-tolyl) from experiment and DFT-calculations. Geometrical and ground state electronic structures of nitrosylcobalt complexes [(RNCHCHNR)Co(NO)(CO)] (R = isopropyl, 2,6-diisopropylphenyl or p-tolyl) from experiment and DFT-calculations.
skos:notation
RIV/61388955:_____/02:54020193!RIV/2003/AV0/A54003/N
n3:strany
2360;2364
n3:aktivita
n7:Z n7:P
n3:aktivity
P(OC D14.20), Z(AV0Z4040901)
n3:cisloPeriodika
N/A
n3:dodaniDat
n9:2003
n3:domaciTvurceVysledku
n11:3953084
n3:druhVysledku
n18:J
n3:duvernostUdaju
n8:S
n3:entitaPredkladatele
n14:predkladatel
n3:idSjednocenehoVysledku
647084
n3:idVysledku
RIV/61388955:_____/02:54020193
n3:jazykVysledku
n16:eng
n3:klicovaSlova
carbonyl complexes; cobalt compounds; DFT calculations
n3:klicoveSlovo
n13:DFT%20calculations n13:carbonyl%20complexes n13:cobalt%20compounds
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[F5E4AE2AD800]
n3:nazevZdroje
Zeitschrift für Anorganische und Allgemeine Chemie
n3:obor
n6:CF
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
6
n3:pocetUcastnikuAkce
0
n3:pocetZahranicnichUcastnikuAkce
0
n3:projekt
n10:OC%20D14.20
n3:rokUplatneniVysledku
n9:2002
n3:svazekPeriodika
628
n3:tvurceVysledku
Kaim, W. Hubler, K. Scheiring, T. Sieger, M. Záliš, Stanislav Sixt, T.
n3:zamer
n17:AV0Z4040901
s:issn
0044-2313
s:numberOfPages
5