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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F02%3A54020182%21RIV%2F2003%2FAV0%2FA54003%2FN
rdf:type
n6:Vysledek skos:Concept
dcterms:description
The low-lying electronic transitions and photochemical reactions of a series of [(Pr-i-DAB)Pt(R)(2)] (where the co-ligand R = CH3, CD3, adme, neop, neoSi, Cequivalent toC(t)Bu, Cequivalent toCPh, Ph, Mes) compounds were studied using both experimental (electronic absorption and resonance Raman spectroscopy) and theoretical (density functional theory, DFT) techniques. The high-lying filled orbitals were revealed to have a significant co-ligand contribution in the case of alkyl complexes, while this contribution is predominant for the complexes with unsaturated co-ligands. Because the electronic transition removes electron density from the sigma(Pt-C) bond in the former complexes, it is best described as a metal-to-ligand charge transfer transition (MLCT) with partial sigma-bond-to-ligand charge transfer (SBLCT) character. Because the sigma(Pt-C) orbital is not involved in the HOMOs of the latter complexes, the low-lying transitions were characterized. The low-lying electronic transitions and photochemical reactions of a series of [(Pr-i-DAB)Pt(R)(2)] (where the co-ligand R = CH3, CD3, adme, neop, neoSi, Cequivalent toC(t)Bu, Cequivalent toCPh, Ph, Mes) compounds were studied using both experimental (electronic absorption and resonance Raman spectroscopy) and theoretical (density functional theory, DFT) techniques. The high-lying filled orbitals were revealed to have a significant co-ligand contribution in the case of alkyl complexes, while this contribution is predominant for the complexes with unsaturated co-ligands. Because the electronic transition removes electron density from the sigma(Pt-C) bond in the former complexes, it is best described as a metal-to-ligand charge transfer transition (MLCT) with partial sigma-bond-to-ligand charge transfer (SBLCT) character. Because the sigma(Pt-C) orbital is not involved in the HOMOs of the latter complexes, the low-lying transitions were characterized.
dcterms:title
Participation of Co-Ligands in Electronic Transitions of Platinum(II) Diazabutadiene Complexes. Participation of Co-Ligands in Electronic Transitions of Platinum(II) Diazabutadiene Complexes.
skos:prefLabel
Participation of Co-Ligands in Electronic Transitions of Platinum(II) Diazabutadiene Complexes. Participation of Co-Ligands in Electronic Transitions of Platinum(II) Diazabutadiene Complexes.
skos:notation
RIV/61388955:_____/02:54020182!RIV/2003/AV0/A54003/N
n3:strany
5216;5225
n3:aktivita
n10:P n10:Z
n3:aktivity
P(ME 439), P(OC D14.20), Z(AV0Z4040901)
n3:cisloPeriodika
20
n3:dodaniDat
n14:2003
n3:domaciTvurceVysledku
n16:3953084
n3:druhVysledku
n11:J
n3:duvernostUdaju
n15:S
n3:entitaPredkladatele
n5:predkladatel
n3:idSjednocenehoVysledku
657838
n3:idVysledku
RIV/61388955:_____/02:54020182
n3:jazykVysledku
n18:eng
n3:klicovaSlova
molecular photochemical device; resonance Raman-spectra; alpha-diimine ligands
n3:klicoveSlovo
n12:molecular%20photochemical%20device n12:alpha-diimine%20ligands n12:resonance%20Raman-spectra
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[9772B4CCD62E]
n3:nazevZdroje
Inorganic Chemistry
n3:obor
n4:CF
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
3
n3:pocetUcastnikuAkce
0
n3:pocetZahranicnichUcastnikuAkce
0
n3:projekt
n9:ME%20439 n9:OC%20D14.20
n3:rokUplatneniVysledku
n14:2002
n3:svazekPeriodika
41
n3:tvurceVysledku
Záliš, Stanislav Klein, A. Slageren van, J.
n3:zamer
n17:AV0Z4040901
s:issn
0020-1669
s:numberOfPages
10