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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F02%3A54020011%21RIV%2F2003%2FAV0%2FA54003%2FN
rdf:type
skos:Concept n17:Vysledek
dcterms:description
A multivariate curve resolution method by alternating least squares is applied to differential pulse voltammograms measured on the Cd(II)+(.gamma.-Glu-Cys)2 Gly system as a model of metal-phytochelatin interactions. The combined analysis of both matrices from titrations of peptide with metal and of metal with peptide (concentration range 10-7 to 10-5 mol1-1) allowed the resolution of the system. The analysis of the resulting pure voltammograms and concentration profiles of the resolved components suggested the presence of four different types of bound Cd(II) and made possible the formulation of a complexation model. A multivariate curve resolution method by alternating least squares is applied to differential pulse voltammograms measured on the Cd(II)+(.gamma.-Glu-Cys)2 Gly system as a model of metal-phytochelatin interactions. The combined analysis of both matrices from titrations of peptide with metal and of metal with peptide (concentration range 10-7 to 10-5 mol1-1) allowed the resolution of the system. The analysis of the resulting pure voltammograms and concentration profiles of the resolved components suggested the presence of four different types of bound Cd(II) and made possible the formulation of a complexation model.
dcterms:title
Differential Pulse Voltammetric Study of the Complexation of Cd(II) by the Phytochelatin (.gamma. -Glu-Cys)2Gly Assisted by Multivariate Curve Resolution. Differential Pulse Voltammetric Study of the Complexation of Cd(II) by the Phytochelatin (.gamma. -Glu-Cys)2Gly Assisted by Multivariate Curve Resolution.
skos:prefLabel
Differential Pulse Voltammetric Study of the Complexation of Cd(II) by the Phytochelatin (.gamma. -Glu-Cys)2Gly Assisted by Multivariate Curve Resolution. Differential Pulse Voltammetric Study of the Complexation of Cd(II) by the Phytochelatin (.gamma. -Glu-Cys)2Gly Assisted by Multivariate Curve Resolution.
skos:notation
RIV/61388955:_____/02:54020011!RIV/2003/AV0/A54003/N
n3:strany
111;118
n3:aktivita
n4:P n4:Z
n3:aktivity
P(GV204/97/K084), Z(AV0Z4040901), Z(AV0Z4055905)
n3:cisloPeriodika
1/2
n3:dodaniDat
n13:2003
n3:domaciTvurceVysledku
n5:8651957
n3:druhVysledku
n10:J
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n6:predkladatel
n3:idSjednocenehoVysledku
643149
n3:idVysledku
RIV/61388955:_____/02:54020011
n3:jazykVysledku
n9:eng
n3:klicovaSlova
heavy metal speciation; - cadmium; - voltammetry
n3:klicoveSlovo
n7:-%20voltammetry n7:heavy%20metal%20speciation n7:-%20cadmium
n3:kodStatuVydavatele
CH - Švýcarská konfederace
n3:kontrolniKodProRIV
[24E15754D813]
n3:nazevZdroje
Journal of Electroanalytical Chemistry
n3:obor
n18:CG
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
6
n3:pocetUcastnikuAkce
0
n3:pocetZahranicnichUcastnikuAkce
0
n3:projekt
n15:GV204%2F97%2FK084
n3:rokUplatneniVysledku
n13:2002
n3:svazekPeriodika
520
n3:tvurceVysledku
Šestáková, Ivana Arino, Ch. Velek, Jiří Esteban, M. Cruz, B. H. Diaz-Cruz, J. M.
n3:zamer
n8:AV0Z4040901 n8:AV0Z4055905
s:issn
0022-0728
s:numberOfPages
8