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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F01%3A54020117%21RIV%2F2003%2FAV0%2FA54003%2FN
rdf:type
n14:Vysledek skos:Concept
dcterms:description
triazacyclononane, has been crystallized for structural characterization. The results are reproduced by density functional theory (DFT) calculations and confirm the sensitivity of the central Ru(mu-Cl)(3)Ru core to contacts between the Cl bridging atoms and the co-ligands. The singly occupied MO is characterized as a (sigma* MO involving the metal d(z)(2) orbitals and a small halide contribution by DFT calculations and EPR. triazacyclononane, has been crystallized for structural characterization. The results are reproduced by density functional theory (DFT) calculations and confirm the sensitivity of the central Ru(mu-Cl)(3)Ru core to contacts between the Cl bridging atoms and the co-ligands. The singly occupied MO is characterized as a (sigma* MO involving the metal d(z)(2) orbitals and a small halide contribution by DFT calculations and EPR.
dcterms:title
Experimental and DFT Calculated Sructure of the Diruthenium(2.5) Complex [(Me3 TACN)Ru(.mu.-Cl)3Ru(Me3 TACN)](PF6)2. Experimental and DFT Calculated Sructure of the Diruthenium(2.5) Complex [(Me3 TACN)Ru(.mu.-Cl)3Ru(Me3 TACN)](PF6)2.
skos:prefLabel
Experimental and DFT Calculated Sructure of the Diruthenium(2.5) Complex [(Me3 TACN)Ru(.mu.-Cl)3Ru(Me3 TACN)](PF6)2. Experimental and DFT Calculated Sructure of the Diruthenium(2.5) Complex [(Me3 TACN)Ru(.mu.-Cl)3Ru(Me3 TACN)](PF6)2.
skos:notation
RIV/61388955:_____/01:54020117!RIV/2003/AV0/A54003/N
n3:strany
145;148
n3:aktivita
n15:Z n15:P
n3:aktivity
P(OC D14.20), P(OC D15.10), Z(AV0Z4040901)
n3:cisloPeriodika
N/A
n3:dodaniDat
n5:2003
n3:domaciTvurceVysledku
n18:3953084
n3:druhVysledku
n17:J
n3:duvernostUdaju
n11:S
n3:entitaPredkladatele
n13:predkladatel
n3:idSjednocenehoVysledku
679920
n3:idVysledku
RIV/61388955:_____/01:54020117
n3:jazykVysledku
n4:eng
n3:klicovaSlova
ruthenium complex; - electron paramagnetic resonance; - electronic structure
n3:klicoveSlovo
n9:-%20electron%20paramagnetic%20resonance n9:-%20electronic%20structure n9:ruthenium%20complex
n3:kodStatuVydavatele
IL - Stát Izrael
n3:kontrolniKodProRIV
[564117F3A711]
n3:nazevZdroje
Israel Journal of Chemistry
n3:obor
n12:CF
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
5
n3:pocetUcastnikuAkce
0
n3:pocetZahranicnichUcastnikuAkce
0
n3:projekt
n10:OC%20D14.20 n10:OC%20D15.10
n3:rokUplatneniVysledku
n5:2001
n3:svazekPeriodika
41
n3:tvurceVysledku
Titze, C. Klein, A. Knödler, A. Záliš, Stanislav Kaim, W.
n3:zamer
n6:AV0Z4040901
s:issn
0021-2148
s:numberOfPages
4