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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F00%3A54000208%21RIV%2F2003%2FAV0%2FA54003%2FN
rdf:type
skos:Concept n8:Vysledek
dcterms:description
The title compounds has been investigated by infrared spectroelectrochemistry to reveal the occupation of the pi*(bpy)MO on one-electron reduction to radical-anion with negligible participation of the pi-accepting acetyl group.Crystal structure analysis of Re(bpy)(CO) 3 (COCH 3 ) revealed a short C-O(acetyl) and long Re-C(acetyl) bond and an orientation of the Re-C(O)CH 3 plane parallel to C 2 axis of coordinated bpy. The title compounds has been investigated by infrared spectroelectrochemistry to reveal the occupation of the pi*(bpy)MO on one-electron reduction to radical-anion with negligible participation of the pi-accepting acetyl group.Crystal structure analysis of Re(bpy)(CO) 3 (COCH 3 ) revealed a short C-O(acetyl) and long Re-C(acetyl) bond and an orientation of the Re-C(O)CH 3 plane parallel to C 2 axis of coordinated bpy.
dcterms:title
Geometrical and Electronic Structures of the Acetyl Complex Re(bpy)(CO) 3 (COCH 3 ) and of [M(bpy)(CO) 4 ](OTf), M=Mn, Re. Geometrical and Electronic Structures of the Acetyl Complex Re(bpy)(CO) 3 (COCH 3 ) and of [M(bpy)(CO) 4 ](OTf), M=Mn, Re.
skos:prefLabel
Geometrical and Electronic Structures of the Acetyl Complex Re(bpy)(CO) 3 (COCH 3 ) and of [M(bpy)(CO) 4 ](OTf), M=Mn, Re. Geometrical and Electronic Structures of the Acetyl Complex Re(bpy)(CO) 3 (COCH 3 ) and of [M(bpy)(CO) 4 ](OTf), M=Mn, Re.
skos:notation
RIV/61388955:_____/00:54000208!RIV/2003/AV0/A54003/N
n5:strany
136;141
n5:aktivita
n14:Z n14:P
n5:aktivity
P(OC D14.20), Z(AV0Z4040901)
n5:cisloPeriodika
1
n5:dodaniDat
n7:2003
n5:domaciTvurceVysledku
n16:3742121
n5:druhVysledku
n15:J
n5:duvernostUdaju
n13:S
n5:entitaPredkladatele
n10:predkladatel
n5:idSjednocenehoVysledku
711999
n5:idVysledku
RIV/61388955:_____/00:54000208
n5:jazykVysledku
n6:eng
n5:klicovaSlova
N/A
n5:klicoveSlovo
n12:N%2FA
n5:kodStatuVydavatele
CH - Švýcarská konfederace
n5:kontrolniKodProRIV
[264CE526037B]
n5:nazevZdroje
Journal of Organometallic Chemistry
n5:obor
n11:CF
n5:pocetDomacichTvurcuVysledku
1
n5:pocetTvurcuVysledku
3
n5:pocetUcastnikuAkce
0
n5:pocetZahranicnichUcastnikuAkce
0
n5:projekt
n18:OC%20D14.20
n5:rokUplatneniVysledku
n7:2000
n5:svazekPeriodika
598
n5:tvurceVysledku
Kaim, W. Scheiring, Thomas Fiedler, Jan
n5:zamer
n17:AV0Z4040901
s:issn
0022-328X
s:numberOfPages
6