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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F00%3A54000176%21RIV%2F2003%2FAV0%2FA54003%2FN
rdf:type
skos:Concept n11:Vysledek
dcterms:description
The complexes [(DMA)Cu(PPh 3 ) 2 ](BF 4 )(1), [(DMA)Ru(bpy) 2 ](PF 6 ) 2 (2) and (DMA)WOCl 3 (3) with 1,3-dimethylalloxazine (DMA) were obtained as O 4 -N 5 cheladet species, as evident from an X-ray crystal structure analysis for 3and from spectroscopy (NMR, IR and UV/vis spectroelectrochemistry).DFT and ab initio methodology is used to illustrate the correspondence in spin distribution between the anion radical p systems of alloxazine and isoalloxazine. The complexes [(DMA)Cu(PPh 3 ) 2 ](BF 4 )(1), [(DMA)Ru(bpy) 2 ](PF 6 ) 2 (2) and (DMA)WOCl 3 (3) with 1,3-dimethylalloxazine (DMA) were obtained as O 4 -N 5 cheladet species, as evident from an X-ray crystal structure analysis for 3and from spectroscopy (NMR, IR and UV/vis spectroelectrochemistry).DFT and ab initio methodology is used to illustrate the correspondence in spin distribution between the anion radical p systems of alloxazine and isoalloxazine.
dcterms:title
Metal vs. Ligand Reduction in Complexes of 1,3-Dimethylalloxazine (DMA) with Copper(I), Ruthenium(II), and Tungsten(IV). Crystal Structures of (DMA) WO 2 Cl 2 and (Bis(1-methylimidazol-2-yl)ketone)WO 2 Cl 2 . Metal vs. Ligand Reduction in Complexes of 1,3-Dimethylalloxazine (DMA) with Copper(I), Ruthenium(II), and Tungsten(IV). Crystal Structures of (DMA) WO 2 Cl 2 and (Bis(1-methylimidazol-2-yl)ketone)WO 2 Cl 2 .
skos:prefLabel
Metal vs. Ligand Reduction in Complexes of 1,3-Dimethylalloxazine (DMA) with Copper(I), Ruthenium(II), and Tungsten(IV). Crystal Structures of (DMA) WO 2 Cl 2 and (Bis(1-methylimidazol-2-yl)ketone)WO 2 Cl 2 . Metal vs. Ligand Reduction in Complexes of 1,3-Dimethylalloxazine (DMA) with Copper(I), Ruthenium(II), and Tungsten(IV). Crystal Structures of (DMA) WO 2 Cl 2 and (Bis(1-methylimidazol-2-yl)ketone)WO 2 Cl 2 .
skos:notation
RIV/61388955:_____/00:54000176!RIV/2003/AV0/A54003/N
n5:strany
4052;4058
n5:aktivita
n12:P n12:Z
n5:aktivity
P(OC D14.20), Z(AV0Z4040901)
n5:cisloPeriodika
18
n5:dodaniDat
n10:2003
n5:domaciTvurceVysledku
n14:3953084
n5:druhVysledku
n9:J
n5:duvernostUdaju
n15:S
n5:entitaPredkladatele
n18:predkladatel
n5:idSjednocenehoVysledku
717120
n5:idVysledku
RIV/61388955:_____/00:54000176
n5:jazykVysledku
n6:eng
n5:klicovaSlova
N/A
n5:klicoveSlovo
n13:N%2FA
n5:kodStatuVydavatele
US - Spojené státy americké
n5:kontrolniKodProRIV
[25289B9E9AE0]
n5:nazevZdroje
Inorganic Chemistry
n5:obor
n16:CF
n5:pocetDomacichTvurcuVysledku
1
n5:pocetTvurcuVysledku
5
n5:pocetUcastnikuAkce
0
n5:pocetZahranicnichUcastnikuAkce
0
n5:projekt
n17:OC%20D14.20
n5:rokUplatneniVysledku
n10:2000
n5:svazekPeriodika
39
n5:tvurceVysledku
Hornung, F. M. Heilmann, O. Fiedler, Jan Kaim, W. Záliš, Stanislav
n5:zamer
n8:AV0Z4040901
s:issn
0020-1669
s:numberOfPages
7