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Statements

Subject Item
n2:RIV%2F61388955%3A_____%2F00%3A54000073%21RIV%2F2003%2FAV0%2FA54003%2FN
rdf:type
n7:Vysledek skos:Concept
dcterms:description
Photolysis of the HCl molecule surface solvated on clusters with two to twelve argon atoms is investigated by means of quantum molecular dynamics simulations.Two basic questions are addressed: i) How does the cage effect change upon increasing the size of the cluster, and ii) How can caging be influenced by an IR excitation of HCl hindered rotation (libration) prior to UV photolysis. The efficiency of caging is discussed in terms of measurable quantities. Photolysis of the HCl molecule surface solvated on clusters with two to twelve argon atoms is investigated by means of quantum molecular dynamics simulations.Two basic questions are addressed: i) How does the cage effect change upon increasing the size of the cluster, and ii) How can caging be influenced by an IR excitation of HCl hindered rotation (libration) prior to UV photolysis. The efficiency of caging is discussed in terms of measurable quantities.
dcterms:title
HCl Photodissociation on Argon Clusters: Effects of Sequential Solvation and Librational Preexcitation. HCl Photodissociation on Argon Clusters: Effects of Sequential Solvation and Librational Preexcitation.
skos:prefLabel
HCl Photodissociation on Argon Clusters: Effects of Sequential Solvation and Librational Preexcitation. HCl Photodissociation on Argon Clusters: Effects of Sequential Solvation and Librational Preexcitation.
skos:notation
RIV/61388955:_____/00:54000073!RIV/2003/AV0/A54003/N
n3:strany
10761;10766
n3:aktivita
n4:Z n4:P
n3:aktivity
P(IAA4040706), Z(AV0Z4040901)
n3:cisloPeriodika
24
n3:dodaniDat
n12:2003
n3:domaciTvurceVysledku
n11:4619242
n3:druhVysledku
n13:J
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n14:predkladatel
n3:idSjednocenehoVysledku
712275
n3:idVysledku
RIV/61388955:_____/00:54000073
n3:jazykVysledku
n6:eng
n3:klicovaSlova
N/A
n3:klicoveSlovo
n10:N%2FA
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[BE1EC896AF2C]
n3:nazevZdroje
Journal of Chemical Physics
n3:obor
n17:CF
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
3
n3:pocetUcastnikuAkce
0
n3:pocetZahranicnichUcastnikuAkce
0
n3:projekt
n9:IAA4040706
n3:rokUplatneniVysledku
n12:2000
n3:svazekPeriodika
112
n3:tvurceVysledku
Slavíček, Petr Ždánská, Petra Jungwirth, Pavel
n3:zamer
n18:AV0Z4040901
s:issn
0021-9606
s:numberOfPages
6