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Statements

Subject Item
n2:RIV%2F60461373%3A22340%2F13%3A43895638%21RIV14-MSM-22340___
rdf:type
skos:Concept n7:Vysledek
rdfs:seeAlso
http://www.sciencedirect.com/science/article/pii/S0021961413001596
dcterms:description
Density data for dilute aqueous solutions of three alkane-?,?-diols (pentane-1,5-diol, octane-1,8-diol, nonane-1,9-diol) are presented together with standard molar volumes (partial molar volumes at infinite dilution) calculated from the experimental data. The measurements were performed at temperatures from T = 298 K up to T = 573 K. Experimental pressures were slightly above the saturation vapour pressure of water, and (15 and 30) MPa. The data were obtained using a high-temperature high-pressure flow vibrating-tube densimeter. Measured standard molar volumes were combined with data previously published for other members of the homologous series and discussed. Experimental standard molar volumes were correlated as a function of temperature and pressure using an empirical polynomial function. Contributions of the methylene group to the standard molar volume were also evaluated and discussed. Dependences of standard molar volumes on temperature and pressure were analyzed. Density data for dilute aqueous solutions of three alkane-?,?-diols (pentane-1,5-diol, octane-1,8-diol, nonane-1,9-diol) are presented together with standard molar volumes (partial molar volumes at infinite dilution) calculated from the experimental data. The measurements were performed at temperatures from T = 298 K up to T = 573 K. Experimental pressures were slightly above the saturation vapour pressure of water, and (15 and 30) MPa. The data were obtained using a high-temperature high-pressure flow vibrating-tube densimeter. Measured standard molar volumes were combined with data previously published for other members of the homologous series and discussed. Experimental standard molar volumes were correlated as a function of temperature and pressure using an empirical polynomial function. Contributions of the methylene group to the standard molar volume were also evaluated and discussed. Dependences of standard molar volumes on temperature and pressure were analyzed.
dcterms:title
Partial molar volumes of organic solutes in water. XXIV. Selected alkane-?,?-diols at temperatures T = 298 K to 573 K and pressures up to 30 MPa. Partial molar volumes of organic solutes in water. XXIV. Selected alkane-?,?-diols at temperatures T = 298 K to 573 K and pressures up to 30 MPa.
skos:prefLabel
Partial molar volumes of organic solutes in water. XXIV. Selected alkane-?,?-diols at temperatures T = 298 K to 573 K and pressures up to 30 MPa. Partial molar volumes of organic solutes in water. XXIV. Selected alkane-?,?-diols at temperatures T = 298 K to 573 K and pressures up to 30 MPa.
skos:notation
RIV/60461373:22340/13:43895638!RIV14-MSM-22340___
n7:predkladatel
n8:orjk%3A22340
n5:aktivita
n12:Z
n5:aktivity
Z(MSM6046137307)
n5:cisloPeriodika
květen 2013
n5:dodaniDat
n15:2014
n5:domaciTvurceVysledku
n13:7606370
n5:druhVysledku
n18:J
n5:duvernostUdaju
n10:S
n5:entitaPredkladatele
n9:predkladatel
n5:idSjednocenehoVysledku
95422
n5:idVysledku
RIV/60461373:22340/13:43895638
n5:jazykVysledku
n19:eng
n5:klicovaSlova
high pressure; high temperature; nonane-1,9-diol; octane-1,8-diol; pentane-1,5-diol; aqueous alkane-?,?-diols; partial molar volume; density
n5:klicoveSlovo
n6:8-diol n6:octane-1 n6:high%20temperature n6:aqueous%20alkane-%3F n6:density n6:5-diol n6:nonane-1 n6:pentane-1 n6:%3F-diols n6:partial%20molar%20volume n6:high%20pressure n6:9-diol
n5:kodStatuVydavatele
NL - Nizozemsko
n5:kontrolniKodProRIV
[F2D13C19978C]
n5:nazevZdroje
Journal of Chemical Thermodynamics
n5:obor
n17:CF
n5:pocetDomacichTvurcuVysledku
1
n5:pocetTvurcuVysledku
2
n5:rokUplatneniVysledku
n15:2013
n5:svazekPeriodika
64
n5:tvurceVysledku
Hnědkovský, Lubomír Cibulka, Ivan
n5:wos
000321047200029
n5:zamer
n14:MSM6046137307
s:issn
0021-9614
s:numberOfPages
8
n16:doi
10.1016/j.jct.2013.05.004
n21:organizacniJednotka
22340