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Statements

Subject Item
n2:RIV%2F60461373%3A22340%2F13%3A43895555%21RIV14-GA0-22340___
rdf:type
skos:Concept n11:Vysledek
dcterms:description
We present results of a microscopic density functional theory study of wedge filling transitions, at a right-angle wedge, in the presence of dispersionlike wall-fluid forces. Far from the corner the walls of the wedge show a first-order wetting transition at a temperature Tw which is progressively closer to the bulk critical temperature Tc as the strength of the wall forces is reduced. In addition, the meniscus formed near the corner undergoes a filling transition at a temperature Tf {Tw, the value of which is found to be in excellent agreement with macroscopic predictions. We show that the filling transition is first order if it occurs far from the critical point but is continuous if Tf is close to Tc even though the walls still show firstorder wetting behavior. We present results of a microscopic density functional theory study of wedge filling transitions, at a right-angle wedge, in the presence of dispersionlike wall-fluid forces. Far from the corner the walls of the wedge show a first-order wetting transition at a temperature Tw which is progressively closer to the bulk critical temperature Tc as the strength of the wall forces is reduced. In addition, the meniscus formed near the corner undergoes a filling transition at a temperature Tf {Tw, the value of which is found to be in excellent agreement with macroscopic predictions. We show that the filling transition is first order if it occurs far from the critical point but is continuous if Tf is close to Tc even though the walls still show firstorder wetting behavior.
dcterms:title
Critical point wedge filling Critical point wedge filling
skos:prefLabel
Critical point wedge filling Critical point wedge filling
skos:notation
RIV/60461373:22340/13:43895555!RIV14-GA0-22340___
n11:predkladatel
n12:orjk%3A22340
n3:aktivita
n6:P
n3:aktivity
P(GA13-09914S)
n3:cisloPeriodika
16
n3:dodaniDat
n13:2014
n3:domaciTvurceVysledku
n9:6798527
n3:druhVysledku
n19:J
n3:duvernostUdaju
n10:S
n3:entitaPredkladatele
n16:predkladatel
n3:idSjednocenehoVysledku
67317
n3:idVysledku
RIV/60461373:22340/13:43895555
n3:jazykVysledku
n17:eng
n3:klicovaSlova
Wedge filling, critical point, density functional theory
n3:klicoveSlovo
n4:critical%20point n4:Wedge%20filling n4:density%20functional%20theory
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[B3D33B4F2B30]
n3:nazevZdroje
Physical Review Letters
n3:obor
n7:BE
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
2
n3:projekt
n8:GA13-09914S
n3:rokUplatneniVysledku
n13:2013
n3:svazekPeriodika
110
n3:tvurceVysledku
Parry, Andrew Malijevský, Alexandr
n3:wos
000317813800002
s:issn
0031-9007
s:numberOfPages
5
n18:doi
10.1103/PhysRevLett.110.166101
n14:organizacniJednotka
22340