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Statements

Subject Item
n2:RIV%2F60461373%3A22340%2F13%3A43895275%21RIV14-GA0-22340___
rdf:type
n3:Vysledek skos:Concept
rdfs:seeAlso
http://www.sciencedirect.com/science/article/pii/S1383586613001214
dcterms:description
Ionic liquid polymer gel membranes based on poly(vinylidene fluoride-co-hexafluoropropylene) (p(VDF-HFP)) were prepared by solvent casting from a solution in acetone. The membranes contain from 20 wt% to 80 wt% of pure or mixed ionic liquids based on the imidazolium cation: 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIM][TFSI]) and 1-hexadecyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([HdMIM][TFSI]). Both ionic liquids have the fluorinated anion bis(trifluoromethylsulfonyl)imide, which should make them more compatible with a fluoropolymer matrix, while the different tail lengths in the cation give significantly different melting points. The thermal and mechanical properties of the blend membranes were evaluated and compared with the neat polymer. The performance of the membranes was tested in terms of pure gas permeability and selectivity, separation of limonene/carvone mixtures by pervaporation, and influence of a low water content in the feed on separation by the blended membrane Ionic liquid polymer gel membranes based on poly(vinylidene fluoride-co-hexafluoropropylene) (p(VDF-HFP)) were prepared by solvent casting from a solution in acetone. The membranes contain from 20 wt% to 80 wt% of pure or mixed ionic liquids based on the imidazolium cation: 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIM][TFSI]) and 1-hexadecyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([HdMIM][TFSI]). Both ionic liquids have the fluorinated anion bis(trifluoromethylsulfonyl)imide, which should make them more compatible with a fluoropolymer matrix, while the different tail lengths in the cation give significantly different melting points. The thermal and mechanical properties of the blend membranes were evaluated and compared with the neat polymer. The performance of the membranes was tested in terms of pure gas permeability and selectivity, separation of limonene/carvone mixtures by pervaporation, and influence of a low water content in the feed on separation by the blended membrane
dcterms:title
Gas transport properties and pervaporation performance of fluoropolymer gel membranes based on pure and mixed ionic liquids Gas transport properties and pervaporation performance of fluoropolymer gel membranes based on pure and mixed ionic liquids
skos:prefLabel
Gas transport properties and pervaporation performance of fluoropolymer gel membranes based on pure and mixed ionic liquids Gas transport properties and pervaporation performance of fluoropolymer gel membranes based on pure and mixed ionic liquids
skos:notation
RIV/60461373:22340/13:43895275!RIV14-GA0-22340___
n3:predkladatel
n4:orjk%3A22340
n5:aktivita
n8:Z n8:I n8:P
n5:aktivity
I, P(7C11009), P(ED2.1.00/03.0071), P(GA104/08/0600), P(GAP106/10/1194), Z(AV0Z40720504)
n5:cisloPeriodika
1
n5:dodaniDat
n15:2014
n5:domaciTvurceVysledku
n10:1772341 n10:5528984
n5:druhVysledku
n16:J
n5:duvernostUdaju
n6:S
n5:entitaPredkladatele
n14:predkladatel
n5:idSjednocenehoVysledku
76191
n5:idVysledku
RIV/60461373:22340/13:43895275
n5:jazykVysledku
n20:eng
n5:klicovaSlova
Pervaporation; Gas permeability; Ionic liquid membrane
n5:klicoveSlovo
n19:Gas%20permeability n19:Ionic%20liquid%20membrane n19:Pervaporation
n5:kodStatuVydavatele
BE - Belgické království
n5:kontrolniKodProRIV
[3F8C077A4F7D]
n5:nazevZdroje
Separation and Purification technology
n5:obor
n7:CD
n5:pocetDomacichTvurcuVysledku
2
n5:pocetTvurcuVysledku
10
n5:projekt
n22:GAP106%2F10%2F1194 n22:ED2.1.00%2F03.0071 n22:7C11009 n22:GA104%2F08%2F0600
n5:rokUplatneniVysledku
n15:2013
n5:svazekPeriodika
109
n5:tvurceVysledku
Clarizia, Gabriele Friess, Karel Kubička, David Schauer, Jan Jansen, Johannes C. Kačírková, Marie Izák, Pavel Bernardo, Paola Randová, Alena Bazzarelli, Fabio
n5:wos
000319099500012
n5:zamer
n18:AV0Z40720504
s:issn
1383-5866
s:numberOfPages
11
n17:doi
10.1016/j.seppur.2013.02.034
n9:organizacniJednotka
22340