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Statements

Subject Item
n2:RIV%2F60461373%3A22340%2F13%3A43895273%21RIV14-MSM-22340___
rdf:type
n3:Vysledek skos:Concept
rdfs:seeAlso
http://www.sciencedirect.com/science/article/pii/S0032386113001663
dcterms:description
The preparation and characterization of novel PIM-1/silicalite-1 (MFI) mixed matrix membranes (MMMs) are reported. Silicalite-1 crystals of size 350 nm were synthesized and functionalized with 2-phenylethyl groups to favour a higher hydrophobicity in the PIM-1 matrix. MMMs with different functionalized crystal loadings (from 8.4 to 35.5 v%) were prepared, characterized and tested in the separation of ethanol from aqueous mixtures with different concentration (5 and 9 wt%) via pervaporation. Pure gas transport properties were also measured for the MMM with the highest filler loading. The enhancement in both ethanol/water separation factor (5.7 vs. 4.3) and CO2/N-2 selectivity (30 vs. 24) compared to neat PIM-1 indicates a positive effect of the silicalite-1 on the molecular separations investigated. The preparation and characterization of novel PIM-1/silicalite-1 (MFI) mixed matrix membranes (MMMs) are reported. Silicalite-1 crystals of size 350 nm were synthesized and functionalized with 2-phenylethyl groups to favour a higher hydrophobicity in the PIM-1 matrix. MMMs with different functionalized crystal loadings (from 8.4 to 35.5 v%) were prepared, characterized and tested in the separation of ethanol from aqueous mixtures with different concentration (5 and 9 wt%) via pervaporation. Pure gas transport properties were also measured for the MMM with the highest filler loading. The enhancement in both ethanol/water separation factor (5.7 vs. 4.3) and CO2/N-2 selectivity (30 vs. 24) compared to neat PIM-1 indicates a positive effect of the silicalite-1 on the molecular separations investigated.
dcterms:title
New organophilic mixed matrix membranes derived from a polymer of intrinsic microporosity and silicalite-1 New organophilic mixed matrix membranes derived from a polymer of intrinsic microporosity and silicalite-1
skos:prefLabel
New organophilic mixed matrix membranes derived from a polymer of intrinsic microporosity and silicalite-1 New organophilic mixed matrix membranes derived from a polymer of intrinsic microporosity and silicalite-1
skos:notation
RIV/60461373:22340/13:43895273!RIV14-MSM-22340___
n3:predkladatel
n7:orjk%3A22340
n4:aktivita
n16:R
n4:aktivity
R
n4:cisloPeriodika
9
n4:dodaniDat
n5:2014
n4:domaciTvurceVysledku
n12:1680692 n12:1772341
n4:druhVysledku
n17:J
n4:duvernostUdaju
n18:S
n4:entitaPredkladatele
n15:predkladatel
n4:idSjednocenehoVysledku
91642
n4:idVysledku
RIV/60461373:22340/13:43895273
n4:jazykVysledku
n13:eng
n4:klicovaSlova
Mixed matrix membranes; Silicalite-1 (MFI) crystals; Polymer of intrinsic microporosity (PIM-1)
n4:klicoveSlovo
n9:Mixed%20matrix%20membranes n9:Polymer%20of%20intrinsic%20microporosity%20%28PIM-1%29 n9:Silicalite-1%20%28MFI%29%20crystals
n4:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n4:kontrolniKodProRIV
[54ED4C4F07C7]
n4:nazevZdroje
Polymer
n4:obor
n20:CD
n4:pocetDomacichTvurcuVysledku
2
n4:pocetTvurcuVysledku
8
n4:rokUplatneniVysledku
n5:2013
n4:svazekPeriodika
54
n4:tvurceVysledku
Golemme, Giovanni Mason, Christopher R. Hynek, Vladimír Galiano, Francesco Budd, Peter M. Friess, Karel Buonomenna, Maria G. Figoli, Alberto
n4:wos
000317632900002
s:issn
0032-3861
s:numberOfPages
9
n19:doi
10.1016/j.polymer.2013.02.032
n6:organizacniJednotka
22340