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Statements

Subject Item
n2:RIV%2F60461373%3A22340%2F13%3A43895230%21RIV14-GA0-22340___
rdf:type
skos:Concept n5:Vysledek
rdfs:seeAlso
http://onlinelibrary.wiley.com/doi/10.1002/chir.22220/abstract
dcterms:description
Racemic mixtures of six Troger's base derivatives were separated by chiral nonaqueous capillary electrophoresis. The separation protocol was optimized first for suitable solvents. Then the applicability of various salts dissolved in organic solvents and their mixtures was evaluated. As chiral selectors -cyclodextrin and heptakis(2,6-di-O-methyl)--cyclodextrin at various concentrations were used. The best enantioselectivity for the studied analytes was obtained utilizing formamide as organic nonaqueous solvent containing a mixture of sodium citrate and tris(hydroxymethyl)aminomethane acetate as electrolytes, and -cyclodextrin as chiral additive. The experimental results demonstrated the feasibility of nonaqueous capillary electrophoresis for enantioseparation of Troger's base derivatives. This technique represents a suitable alternative to more commonly used capillary electrophoresis in aqueous environment. Chirality 25:810-813, 2013. (c) 2013 Wiley Periodicals, Inc. Racemic mixtures of six Troger's base derivatives were separated by chiral nonaqueous capillary electrophoresis. The separation protocol was optimized first for suitable solvents. Then the applicability of various salts dissolved in organic solvents and their mixtures was evaluated. As chiral selectors -cyclodextrin and heptakis(2,6-di-O-methyl)--cyclodextrin at various concentrations were used. The best enantioselectivity for the studied analytes was obtained utilizing formamide as organic nonaqueous solvent containing a mixture of sodium citrate and tris(hydroxymethyl)aminomethane acetate as electrolytes, and -cyclodextrin as chiral additive. The experimental results demonstrated the feasibility of nonaqueous capillary electrophoresis for enantioseparation of Troger's base derivatives. This technique represents a suitable alternative to more commonly used capillary electrophoresis in aqueous environment. Chirality 25:810-813, 2013. (c) 2013 Wiley Periodicals, Inc.
dcterms:title
Nonaqueous Capillary Electrophoretic Enantioseparation of Water Insoluble Troger's Base Derivatives Using beta-Cyclodextrin as Chiral Selector Nonaqueous Capillary Electrophoretic Enantioseparation of Water Insoluble Troger's Base Derivatives Using beta-Cyclodextrin as Chiral Selector
skos:prefLabel
Nonaqueous Capillary Electrophoretic Enantioseparation of Water Insoluble Troger's Base Derivatives Using beta-Cyclodextrin as Chiral Selector Nonaqueous Capillary Electrophoretic Enantioseparation of Water Insoluble Troger's Base Derivatives Using beta-Cyclodextrin as Chiral Selector
skos:notation
RIV/60461373:22340/13:43895230!RIV14-GA0-22340___
n5:predkladatel
n6:orjk%3A22340
n3:aktivita
n17:P
n3:aktivity
P(GAP206/12/0453)
n3:cisloPeriodika
11
n3:dodaniDat
n4:2014
n3:domaciTvurceVysledku
n9:3087115 n9:2796546 n9:2012707 n9:1123262 n9:7976224
n3:druhVysledku
n18:J
n3:duvernostUdaju
n20:S
n3:entitaPredkladatele
n15:predkladatel
n3:idSjednocenehoVysledku
91903
n3:idVysledku
RIV/60461373:22340/13:43895230
n3:jazykVysledku
n16:eng
n3:klicovaSlova
Troger's base; capillary electrophoresis; nonaqueous; enantioseparation; beta-cyclodextrin; capillary electrophoresis
n3:klicoveSlovo
n13:nonaqueous n13:capillary%20electrophoresis n13:Troger%27s%20base n13:enantioseparation n13:beta-cyclodextrin
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[07A7CC81A2FF]
n3:nazevZdroje
Chirality
n3:obor
n19:CB
n3:pocetDomacichTvurcuVysledku
5
n3:pocetTvurcuVysledku
5
n3:projekt
n10:GAP206%2F12%2F0453
n3:rokUplatneniVysledku
n4:2013
n3:svazekPeriodika
25
n3:tvurceVysledku
Král, Vladimír Novotný, Michal Havlík, Martin Řezanka, Pavel Sýkora, David
n3:wos
000326291700020
s:issn
0899-0042
s:numberOfPages
4
n21:doi
10.1002/chir.22220
n11:organizacniJednotka
22340