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Statements

Subject Item
n2:RIV%2F60461373%3A22340%2F12%3A43893700%21RIV13-GA0-22340___
rdf:type
n13:Vysledek skos:Concept
rdfs:seeAlso
http://www.sciencedirect.com/science/article/pii/S0040603112000032
dcterms:description
Heat capacity and enthalpy increments of ternary strontium bismuth(III) oxides SrBi2O4 and Sr2Bi2O5 were measured by the relaxation time method (2-210 K), DSC (253-352 K) and drop calorimetry (570-1072 K). Temperature dependencies of the molar heat capacity in the form Cpm=161.97+45.936e?3 T - 1.7862e6/T2 JK?1mol?1 and Cpm=197.48+87.463e?3 T - 1.9282e6/T2 JK?1mol?1 for SrBi2O4 and Sr2Bi2O5, respectively, were derived by the least-squares method from the experimental data. The molar entropies at 298.15 K, S°m(298.15 K)=206.1+-1.1 JK?1mol?1 for SrBi2O4 and S°m(298.15 K)=261.2+-1.4 JK?1mol?1 for Sr2Bi2O5, were evaluated from the low temperature heat capacity measurements. Heat capacity and enthalpy increments of ternary strontium bismuth(III) oxides SrBi2O4 and Sr2Bi2O5 were measured by the relaxation time method (2-210 K), DSC (253-352 K) and drop calorimetry (570-1072 K). Temperature dependencies of the molar heat capacity in the form Cpm=161.97+45.936e?3 T - 1.7862e6/T2 JK?1mol?1 and Cpm=197.48+87.463e?3 T - 1.9282e6/T2 JK?1mol?1 for SrBi2O4 and Sr2Bi2O5, respectively, were derived by the least-squares method from the experimental data. The molar entropies at 298.15 K, S°m(298.15 K)=206.1+-1.1 JK?1mol?1 for SrBi2O4 and S°m(298.15 K)=261.2+-1.4 JK?1mol?1 for Sr2Bi2O5, were evaluated from the low temperature heat capacity measurements.
dcterms:title
Heat capacity, enthalpy and entropy of SrBi2O4 and Sr2Bi2O5 Heat capacity, enthalpy and entropy of SrBi2O4 and Sr2Bi2O5
skos:prefLabel
Heat capacity, enthalpy and entropy of SrBi2O4 and Sr2Bi2O5 Heat capacity, enthalpy and entropy of SrBi2O4 and Sr2Bi2O5
skos:notation
RIV/60461373:22340/12:43893700!RIV13-GA0-22340___
n13:predkladatel
n14:orjk%3A22340
n3:aktivita
n15:P n15:Z
n3:aktivity
P(GA203/09/1036), P(GAP108/10/1006), Z(MSM0021620834), Z(MSM6046137302), Z(MSM6046137307)
n3:cisloPeriodika
11.1.2012
n3:dodaniDat
n17:2013
n3:domaciTvurceVysledku
n12:9424466
n3:druhVysledku
n16:J
n3:duvernostUdaju
n18:S
n3:entitaPredkladatele
n19:predkladatel
n3:idSjednocenehoVysledku
138729
n3:idVysledku
RIV/60461373:22340/12:43893700
n3:jazykVysledku
n8:eng
n3:klicovaSlova
Strontium bismuth(III) oxides; Calorimetry; Entropy; Enthalpy increments; Heat capacity
n3:klicoveSlovo
n6:Strontium%20bismuth%28III%29%20oxides n6:Enthalpy%20increments n6:Calorimetry n6:Entropy n6:Heat%20capacity
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[EF4D53A5BAEF]
n3:nazevZdroje
Thermochimica Acta
n3:obor
n22:CA
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
4
n3:projekt
n20:GAP108%2F10%2F1006 n20:GA203%2F09%2F1036
n3:rokUplatneniVysledku
n17:2012
n3:svazekPeriodika
531
n3:tvurceVysledku
Sedmidubský, David Leitner, Jindřich Svoboda, Pavel Růžička, Květoslav
n3:wos
000301309700010
n3:zamer
n7:MSM6046137307 n7:MSM6046137302 n7:MSM0021620834
s:issn
0040-6031
s:numberOfPages
6
n9:doi
10.1016/j.tca.2012.01.002
n5:organizacniJednotka
22340