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Statements

Subject Item
n2:RIV%2F60461373%3A22340%2F12%3A43893420%21RIV13-GA0-22340___
rdf:type
skos:Concept n6:Vysledek
dcterms:description
The article reports on the unique manipulation of the acid-catalyzed reaction of [2-aminoporphyrinato(2-)]nickel with formaldehyde to form selectively either the symmetric Tröger's base or the asymmetric spiro Tröger's base bis(metalloporphyrin) derivative. The reaction is driven by the choice of acid catalyst, formaldehyde source, and particularly, solvent, to give a mixture of both derivatives in preparative yields of about 90%, or to give selectively one of the derivatives in a yield of about 60%. The article reports on the unique manipulation of the acid-catalyzed reaction of [2-aminoporphyrinato(2-)]nickel with formaldehyde to form selectively either the symmetric Tröger's base or the asymmetric spiro Tröger's base bis(metalloporphyrin) derivative. The reaction is driven by the choice of acid catalyst, formaldehyde source, and particularly, solvent, to give a mixture of both derivatives in preparative yields of about 90%, or to give selectively one of the derivatives in a yield of about 60%.
dcterms:title
Selective formation of either Tröger's base or spiro Tröger's base derivatives from [2-aminoporphyrinato(2-)]nickel by choice of reaction conditions Selective formation of either Tröger's base or spiro Tröger's base derivatives from [2-aminoporphyrinato(2-)]nickel by choice of reaction conditions
skos:prefLabel
Selective formation of either Tröger's base or spiro Tröger's base derivatives from [2-aminoporphyrinato(2-)]nickel by choice of reaction conditions Selective formation of either Tröger's base or spiro Tröger's base derivatives from [2-aminoporphyrinato(2-)]nickel by choice of reaction conditions
skos:notation
RIV/60461373:22340/12:43893420!RIV13-GA0-22340___
n6:predkladatel
n7:orjk%3A22340
n5:aktivita
n14:P
n5:aktivity
P(GA203/08/1445)
n5:cisloPeriodika
45
n5:dodaniDat
n8:2013
n5:domaciTvurceVysledku
n9:3698106 Tatar, Ameneh n9:2796546
n5:druhVysledku
n17:J
n5:duvernostUdaju
n20:S
n5:entitaPredkladatele
n13:predkladatel
n5:idSjednocenehoVysledku
167319
n5:idVysledku
RIV/60461373:22340/12:43893420
n5:jazykVysledku
n12:eng
n5:klicovaSlova
Selectivity; Solvent effect; Spiro Tröger's base derivative; Tröger's base derivative; Bis(metalloporphyrin)
n5:klicoveSlovo
n11:Tr%C3%B6ger%27s%20base%20derivative n11:Solvent%20effect n11:Selectivity n11:Spiro%20Tr%C3%B6ger%27s%20base%20derivative n11:Bis%28metalloporphyrin%29
n5:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n5:kontrolniKodProRIV
[1E6DE00CE856]
n5:nazevZdroje
Tetrahedron Letters
n5:obor
n10:CB
n5:pocetDomacichTvurcuVysledku
3
n5:pocetTvurcuVysledku
4
n5:projekt
n16:GA203%2F08%2F1445
n5:rokUplatneniVysledku
n8:2012
n5:svazekPeriodika
53
n5:tvurceVysledku
Tatar, Ameneh Král, Vladimír Dolenský, Bohumil Dvořáková, Hana
n5:wos
000310760800009
s:issn
0040-4039
s:numberOfPages
3
n18:doi
10.1016/j.tetlet.2012.08.097
n19:organizacniJednotka
22340