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Statements

Subject Item
n2:RIV%2F60461373%3A22340%2F12%3A43893334%21RIV13-MSM-22340___
rdf:type
skos:Concept n16:Vysledek
dcterms:description
From extraction experiments and ?-activity measurements, the extraction constant corresponding to the equilibrium Li+(aq) + 1.Na+(nb) ? 1.Li+(nb) + Na+(aq) taking place in the two-phase water-nitrobenzene system (1 = beauvericin; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log Kex(1.Na+) = 0.5 +- 0.1. Further, the stability constant of the 1.Li+ complex in nitrobenzene saturated with water was calculated for a temperature of 25 oC as log ?nb(1.Li+) = 5.6 +- 0.2. By using DFT calculations, the most probable structures of the non-hydrated 1.Li+ and hydrated 1.Li.3H2O complex species were predicted. From extraction experiments and ?-activity measurements, the extraction constant corresponding to the equilibrium Li+(aq) + 1.Na+(nb) ? 1.Li+(nb) + Na+(aq) taking place in the two-phase water-nitrobenzene system (1 = beauvericin; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log Kex(1.Na+) = 0.5 +- 0.1. Further, the stability constant of the 1.Li+ complex in nitrobenzene saturated with water was calculated for a temperature of 25 oC as log ?nb(1.Li+) = 5.6 +- 0.2. By using DFT calculations, the most probable structures of the non-hydrated 1.Li+ and hydrated 1.Li.3H2O complex species were predicted.
dcterms:title
Complexation of the lithium cation with beauvericin: Experimental and DFT study Complexation of the lithium cation with beauvericin: Experimental and DFT study
skos:prefLabel
Complexation of the lithium cation with beauvericin: Experimental and DFT study Complexation of the lithium cation with beauvericin: Experimental and DFT study
skos:notation
RIV/60461373:22340/12:43893334!RIV13-MSM-22340___
n16:predkladatel
n19:orjk%3A22340
n3:aktivita
n15:Z n15:I n15:S n15:P
n3:aktivity
I, P(GAP205/10/2280), S, Z(AV0Z40500505)
n3:cisloPeriodika
may
n3:dodaniDat
n4:2013
n3:domaciTvurceVysledku
n9:9665803
n3:druhVysledku
n17:J
n3:duvernostUdaju
n12:S
n3:entitaPredkladatele
n18:predkladatel
n3:idSjednocenehoVysledku
128201
n3:idVysledku
RIV/60461373:22340/12:43893334
n3:jazykVysledku
n8:eng
n3:klicovaSlova
Structure; Beauvericin; Lithium; Complexation; DFT; Extraction
n3:klicoveSlovo
n10:DFT n10:Beauvericin n10:Structure n10:Complexation n10:Lithium n10:Extraction
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[642309A75FCB]
n3:nazevZdroje
Journal of Molecular Structure
n3:obor
n21:CB
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
3
n3:projekt
n14:GAP205%2F10%2F2280
n3:rokUplatneniVysledku
n4:2012
n3:svazekPeriodika
1024
n3:tvurceVysledku
Makrlík, Emanuel Vaňura, Petr Toman, Petr
n3:wos
000309022400019
n3:zamer
n6:AV0Z40500505
s:issn
0022-2860
s:numberOfPages
4
n13:doi
10.1016/j.molstruc.2012.05.009
n20:organizacniJednotka
22340