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Statements

Subject Item
n2:RIV%2F60461373%3A22340%2F12%3A43893261%21RIV13-MSM-22340___
rdf:type
n8:Vysledek skos:Concept
dcterms:description
From extraction experiments and gama-activity measurements, the extraction constant corresponding to the equilibrium Cs+ (aq) + A? (aq) + 1(nb) ? 1?Cs+(nb) + A?(nb) taking place in the two-phase water-nitrobenzene system (A? = picrate, 1 = dibenzo-30-crown-10; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log Kex (1?Cs+,A?) = 4.0 +- 0.1. Further, the stability constant of the 1?Cs+ complex in nitrobenzene saturated with water was calculated for a temperature of 25 °C: log betanb (1?Cs+) = 5.9 +- 0.1. Finally, by using quantum-mechanical DFT calculations, the most probable structure of the resulting cationic complex species 1?Cs+ was derived. From extraction experiments and gama-activity measurements, the extraction constant corresponding to the equilibrium Cs+ (aq) + A? (aq) + 1(nb) ? 1?Cs+(nb) + A?(nb) taking place in the two-phase water-nitrobenzene system (A? = picrate, 1 = dibenzo-30-crown-10; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log Kex (1?Cs+,A?) = 4.0 +- 0.1. Further, the stability constant of the 1?Cs+ complex in nitrobenzene saturated with water was calculated for a temperature of 25 °C: log betanb (1?Cs+) = 5.9 +- 0.1. Finally, by using quantum-mechanical DFT calculations, the most probable structure of the resulting cationic complex species 1?Cs+ was derived.
dcterms:title
Experimental and theoretical study on the complexation of the cesium cation with dibenzo-30-crown-10 Experimental and theoretical study on the complexation of the cesium cation with dibenzo-30-crown-10
skos:prefLabel
Experimental and theoretical study on the complexation of the cesium cation with dibenzo-30-crown-10 Experimental and theoretical study on the complexation of the cesium cation with dibenzo-30-crown-10
skos:notation
RIV/60461373:22340/12:43893261!RIV13-MSM-22340___
n8:predkladatel
n9:orjk%3A22340
n4:aktivita
n14:S n14:P n14:Z
n4:aktivity
P(GAP205/10/2280), S, Z(AV0Z40500505)
n4:cisloPeriodika
3
n4:dodaniDat
n19:2013
n4:domaciTvurceVysledku
n11:9665803
n4:druhVysledku
n16:J
n4:duvernostUdaju
n20:S
n4:entitaPredkladatele
n13:predkladatel
n4:idSjednocenehoVysledku
135538
n4:idVysledku
RIV/60461373:22340/12:43893261
n4:jazykVysledku
n6:eng
n4:klicovaSlova
DFT calculations; Stability constant; Nitrobenzene; Dibenzo-30-crown-10; Extraction; Picrate; Cesium
n4:klicoveSlovo
n10:Picrate n10:Dibenzo-30-crown-10 n10:Stability%20constant n10:Nitrobenzene n10:Extraction n10:Cesium n10:DFT%20calculations
n4:kodStatuVydavatele
DE - Spolková republika Německo
n4:kontrolniKodProRIV
[6BF3C2E1D6E5]
n4:nazevZdroje
Journal of Radioanalytical and Nuclear Chemistry
n4:obor
n18:CB
n4:pocetDomacichTvurcuVysledku
1
n4:pocetTvurcuVysledku
3
n4:projekt
n15:GAP205%2F10%2F2280
n4:rokUplatneniVysledku
n19:2012
n4:svazekPeriodika
292
n4:tvurceVysledku
Toman, P. Makrlík, Emanuel Vaňura, Petr
n4:wos
000305232400029
n4:zamer
n12:AV0Z40500505
s:issn
0236-5731
s:numberOfPages
4
n7:doi
10.1007/s10967-011-1598-5
n21:organizacniJednotka
22340