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Statements

Subject Item
n2:RIV%2F60461373%3A22340%2F11%3A43891825%21RIV12-MSM-22340___
rdf:type
n7:Vysledek skos:Concept
dcterms:description
The millimeter-wave rotational spectrum of TiO(2) in its ground vibrational state has been recorded in the frequency range from 248 to 345 GHz using the Cologne Supersonic Jet Spectrometer for Terahertz Applications (SuJeSTA). Forty-two b-type rotational transitions of the main isotopologue (48)TiO(2) and five transitions of (46)TiO(2) in natural abundance have been measured up to J = 22 and K(a) = 8 which corresponds to excitation temperatures of 170 K. TiO(2) was formed by laser ablation and adiabatically cooled in a supersonic jet of helium to rotational temperatures of 20 K. The new transitions have been analyzed together with previously reported data obtained from Fourier-transform microwave spectroscopy in the frequency range from 7 to 42 GHz. The improved and extended set of spectroscopic parameters provides accurate transition frequencies for future astronomical searches in the millimeter-wave region. The millimeter-wave rotational spectrum of TiO(2) in its ground vibrational state has been recorded in the frequency range from 248 to 345 GHz using the Cologne Supersonic Jet Spectrometer for Terahertz Applications (SuJeSTA). Forty-two b-type rotational transitions of the main isotopologue (48)TiO(2) and five transitions of (46)TiO(2) in natural abundance have been measured up to J = 22 and K(a) = 8 which corresponds to excitation temperatures of 170 K. TiO(2) was formed by laser ablation and adiabatically cooled in a supersonic jet of helium to rotational temperatures of 20 K. The new transitions have been analyzed together with previously reported data obtained from Fourier-transform microwave spectroscopy in the frequency range from 7 to 42 GHz. The improved and extended set of spectroscopic parameters provides accurate transition frequencies for future astronomical searches in the millimeter-wave region.
dcterms:title
Millimeter-wave spectroscopy of titanium dioxide, TiO(2) Millimeter-wave spectroscopy of titanium dioxide, TiO(2)
skos:prefLabel
Millimeter-wave spectroscopy of titanium dioxide, TiO(2) Millimeter-wave spectroscopy of titanium dioxide, TiO(2)
skos:notation
RIV/60461373:22340/11:43891825!RIV12-MSM-22340___
n7:predkladatel
n9:orjk%3A22340
n3:aktivita
n8:V
n3:aktivity
V
n3:cisloPeriodika
1
n3:dodaniDat
n12:2012
n3:domaciTvurceVysledku
n16:2917114
n3:druhVysledku
n11:J
n3:duvernostUdaju
n10:S
n3:entitaPredkladatele
n17:predkladatel
n3:idSjednocenehoVysledku
212549
n3:idVysledku
RIV/60461373:22340/11:43891825
n3:jazykVysledku
n19:eng
n3:klicovaSlova
Millimeter-wave spectroscopy; Interstellar molecule; Transition metal; Titanium dioxide
n3:klicoveSlovo
n5:Titanium%20dioxide n5:Millimeter-wave%20spectroscopy n5:Interstellar%20molecule n5:Transition%20metal
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[E32E9AAD60E7]
n3:nazevZdroje
Journal of Molecular Spectroscopy
n3:obor
n18:CB
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
5
n3:rokUplatneniVysledku
n12:2011
n3:svazekPeriodika
268
n3:tvurceVysledku
Kania, Patrik Hermanns, Marius Müller, Holger S. P. Giesen, Thomas F. Brünken, Sandra
n3:wos
000294833100024
s:issn
0022-2852
s:numberOfPages
4
n13:doi
10.1016/j.jms.2011.04.013
n14:organizacniJednotka
22340