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Statements

Subject Item
n2:RIV%2F60461373%3A22340%2F11%3A43885713%21RIV12-MSM-22340___
rdf:type
skos:Concept n16:Vysledek
dcterms:description
From extn. expts. and ?-activity measurements, the exchange extn. consts. corresponding to the general equil. M+ (aq) + NaL+ (nb) = ML+ (nb) + Na+ (aq) taking place in the two-phase water-nitrobenzene system (M+ = H3O+, , Ag+, Tl+; L = hexaethyl p-tert-butylcalix[6]arene hexaacetate; aq = aq. phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability consts. of the ML+ complexes in nitrobenzene satd. with water were calcd.; they were found to increase in the following order: order: Ag+ { NH4+ { H3O+ { Na+ { Tl+. From extn. expts. and ?-activity measurements, the exchange extn. consts. corresponding to the general equil. M+ (aq) + NaL+ (nb) = ML+ (nb) + Na+ (aq) taking place in the two-phase water-nitrobenzene system (M+ = H3O+, , Ag+, Tl+; L = hexaethyl p-tert-butylcalix[6]arene hexaacetate; aq = aq. phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability consts. of the ML+ complexes in nitrobenzene satd. with water were calcd.; they were found to increase in the following order: order: Ag+ { NH4+ { H3O+ { Na+ { Tl+.
dcterms:title
Synergistic extraction of some univalent cations into nitrobenzene by using sodium dicarbollylcobaltate and hexaethyl p-tert-butylcalix[6]arene hexaacetate Synergistic extraction of some univalent cations into nitrobenzene by using sodium dicarbollylcobaltate and hexaethyl p-tert-butylcalix[6]arene hexaacetate
skos:prefLabel
Synergistic extraction of some univalent cations into nitrobenzene by using sodium dicarbollylcobaltate and hexaethyl p-tert-butylcalix[6]arene hexaacetate Synergistic extraction of some univalent cations into nitrobenzene by using sodium dicarbollylcobaltate and hexaethyl p-tert-butylcalix[6]arene hexaacetate
skos:notation
RIV/60461373:22340/11:43885713!RIV12-MSM-22340___
n16:predkladatel
n20:orjk%3A22340
n3:aktivita
n7:Z n7:S
n3:aktivity
S, Z(MSM4977751303)
n3:cisloPeriodika
3
n3:dodaniDat
n5:2012
n3:domaciTvurceVysledku
n18:9665803
n3:druhVysledku
n13:J
n3:duvernostUdaju
n4:S
n3:entitaPredkladatele
n12:predkladatel
n3:idSjednocenehoVysledku
233798
n3:idVysledku
RIV/60461373:22340/11:43885713
n3:jazykVysledku
n14:eng
n3:klicovaSlova
Stability constants; Nitrobenzene; Extraction; Dicarbollylcobaltate; Univalent cations; Hexaethyl p-tert-butylcalix[6]arenehexaacetate
n3:klicoveSlovo
n8:Stability%20constants n8:Extraction n8:Dicarbollylcobaltate n8:Univalent%20cations n8:Nitrobenzene n8:Hexaethyl%20p-tert-butylcalix%5B6%5Darenehexaacetate
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[0D7AFC8DD4F4]
n3:nazevZdroje
Journal of Radioanalytical and Nuclear Chemistry
n3:obor
n6:CB
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
2
n3:rokUplatneniVysledku
n5:2011
n3:svazekPeriodika
289
n3:tvurceVysledku
Makrlík, Emanuel Vaňura, Petr
n3:wos
000293029200002
n3:zamer
n10:MSM4977751303
s:issn
0236-5731
s:numberOfPages
4
n17:doi
10.1007/s10967-010-0929-2
n15:organizacniJednotka
22340