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Statements

Subject Item
n2:RIV%2F60461373%3A22340%2F11%3A43881493%21RIV12-MSM-22340___
rdf:type
skos:Concept n8:Vysledek
dcterms:description
From extraction experiments and gama-activity measurements, the exchange extraction constants corresponding to the general equilibrium M+ (aq) + 1?Na+ (nb) = 1?M+ (nb) + Na+ (aq) taking place in the two-phase water?nitrobenzene system (M+ = Li+, H3O+, NH4+, Ag+, K+, Rb+, Tl+, Cs+; 1 = barium ionophore I; aq = aqueous phase, nb = nitrobenzene phase) were determined. Furthermore, the stability constants of the 1?M+ complexes in water-saturated nitrobenzene were calculated; they were found to increase in the series of Cs+ { Rb+ { NH4+, K+ { H3O+ { Na+ { Ag+, Tl+ { Li+. From extraction experiments and gama-activity measurements, the exchange extraction constants corresponding to the general equilibrium M+ (aq) + 1?Na+ (nb) = 1?M+ (nb) + Na+ (aq) taking place in the two-phase water?nitrobenzene system (M+ = Li+, H3O+, NH4+, Ag+, K+, Rb+, Tl+, Cs+; 1 = barium ionophore I; aq = aqueous phase, nb = nitrobenzene phase) were determined. Furthermore, the stability constants of the 1?M+ complexes in water-saturated nitrobenzene were calculated; they were found to increase in the series of Cs+ { Rb+ { NH4+, K+ { H3O+ { Na+ { Ag+, Tl+ { Li+.
dcterms:title
Extraction of some univalent cations into nitrobenzene by using a synergistic mixture of sodium dicarbollylcobaltate and barium ionophore I Extraction of some univalent cations into nitrobenzene by using a synergistic mixture of sodium dicarbollylcobaltate and barium ionophore I
skos:prefLabel
Extraction of some univalent cations into nitrobenzene by using a synergistic mixture of sodium dicarbollylcobaltate and barium ionophore I Extraction of some univalent cations into nitrobenzene by using a synergistic mixture of sodium dicarbollylcobaltate and barium ionophore I
skos:notation
RIV/60461373:22340/11:43881493!RIV12-MSM-22340___
n8:predkladatel
n9:orjk%3A22340
n3:aktivita
n14:Z n14:S
n3:aktivity
S, Z(MSM4977751303)
n3:cisloPeriodika
1
n3:dodaniDat
n13:2012
n3:domaciTvurceVysledku
n19:9665803
n3:druhVysledku
n18:J
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n7:predkladatel
n3:idSjednocenehoVysledku
199102
n3:idVysledku
RIV/60461373:22340/11:43881493
n3:jazykVysledku
n10:eng
n3:klicovaSlova
Stability constants; Barium ionophore I; Dicarbollylcobaltate; Nitrobenzene; Extraction; Univalent cations
n3:klicoveSlovo
n5:Extraction n5:Dicarbollylcobaltate n5:Univalent%20cations n5:Stability%20constants n5:Nitrobenzene n5:Barium%20ionophore%20I
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[1560E1717D47]
n3:nazevZdroje
Journal of Radioanalytical and Nuclear Chemistry
n3:obor
n11:CB
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
2
n3:rokUplatneniVysledku
n13:2011
n3:svazekPeriodika
289
n3:tvurceVysledku
Vaňura, Petr Makrlík, Emanuel
n3:wos
000291359000004
n3:zamer
n12:MSM4977751303
s:issn
0236-5731
s:numberOfPages
4
n17:doi
10.1007/s10967-011-1043-9
n20:organizacniJednotka
22340