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Statements

Subject Item
n2:RIV%2F60461373%3A22340%2F10%3A00023430%21RIV11-MSM-22340___
rdf:type
skos:Concept n9:Vysledek
dcterms:description
The formation of inclusion complex of beta-cyclodextrin (beta-CD) with the hydrophobic room temperature ionic liquid l-butyl-3-methylimidazolium hexafluorophosphate (bmimPF6) in aqueous sofutions was studied at 298.15 K using lH, l3C, 19F and 3lP NMR spectroscopy and isothermal titration calorimetry (ITC). Cunently, there is a disagreement in the literature concerning the structure of the complex formed. In contrast to some results published recently in the literature, we found no reasonable support for beta-CD to form an inclusion complex with 1-buty|-3-methylimidazolium cation of bmimPF6 in water. Our measurements on bmimPF6, the ionic liquid l-butyl-3-methylimidazolium chloride (bmimCl), and the inorganic salt potassium hexafluorophosphate (KPF6) consistently support the formation of a weak l: l inclusion complex of beta-CD with hexafluorophosphate anion instead of the bmim cation. The thermodynamic parameters of the respective complexation were calculated. The binding constant was evaluated from I The formation of inclusion complex of beta-cyclodextrin (beta-CD) with the hydrophobic room temperature ionic liquid l-butyl-3-methylimidazolium hexafluorophosphate (bmimPF6) in aqueous sofutions was studied at 298.15 K using lH, l3C, 19F and 3lP NMR spectroscopy and isothermal titration calorimetry (ITC). Cunently, there is a disagreement in the literature concerning the structure of the complex formed. In contrast to some results published recently in the literature, we found no reasonable support for beta-CD to form an inclusion complex with 1-buty|-3-methylimidazolium cation of bmimPF6 in water. Our measurements on bmimPF6, the ionic liquid l-butyl-3-methylimidazolium chloride (bmimCl), and the inorganic salt potassium hexafluorophosphate (KPF6) consistently support the formation of a weak l: l inclusion complex of beta-CD with hexafluorophosphate anion instead of the bmim cation. The thermodynamic parameters of the respective complexation were calculated. The binding constant was evaluated from I
dcterms:title
On the Interaction of Ionic Liquid l-Butyl-3-Methylimidazolium Hexafluorophosphate with beta-Cyclodextrin in Aqueous Solutions On the Interaction of Ionic Liquid l-Butyl-3-Methylimidazolium Hexafluorophosphate with beta-Cyclodextrin in Aqueous Solutions
skos:prefLabel
On the Interaction of Ionic Liquid l-Butyl-3-Methylimidazolium Hexafluorophosphate with beta-Cyclodextrin in Aqueous Solutions On the Interaction of Ionic Liquid l-Butyl-3-Methylimidazolium Hexafluorophosphate with beta-Cyclodextrin in Aqueous Solutions
skos:notation
RIV/60461373:22340/10:00023430!RIV11-MSM-22340___
n4:aktivita
n16:Z
n4:aktivity
Z(MSM6046137307)
n4:cisloPeriodika
6
n4:dodaniDat
n15:2011
n4:domaciTvurceVysledku
n5:8169985 n5:9628924 n5:9659099 n5:8961131
n4:druhVysledku
n12:J
n4:duvernostUdaju
n17:S
n4:entitaPredkladatele
n11:predkladatel
n4:idSjednocenehoVysledku
276873
n4:idVysledku
RIV/60461373:22340/10:00023430
n4:jazykVysledku
n10:eng
n4:klicovaSlova
BmimPF6; Calorimetry; Cyclodextrins; Ionic liquids; NMR
n4:klicoveSlovo
n7:BmimPF6 n7:Calorimetry n7:Cyclodextrins n7:NMR n7:Ionic%20liquids
n4:kodStatuVydavatele
DE - Spolková republika Německo
n4:kontrolniKodProRIV
[028AAF1535C0]
n4:nazevZdroje
Zeitschrift für Physikalische Chemie
n4:obor
n18:BJ
n4:pocetDomacichTvurcuVysledku
4
n4:pocetTvurcuVysledku
4
n4:rokUplatneniVysledku
n15:2010
n4:svazekPeriodika
224
n4:tvurceVysledku
Dohnal, Vladimír Ondo, Daniel Rak, Jakub Tkadlecová, Marcela
n4:wos
000281120900007
n4:zamer
n13:MSM6046137307
s:issn
0942-9352
s:numberOfPages
14
n14:organizacniJednotka
22340