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Statements

Subject Item
n2:RIV%2F60461373%3A22340%2F08%3A00020714%21RIV09-MSM-22340___
rdf:type
skos:Concept n18:Vysledek
dcterms:description
Na základě extrakčních dat byla počtena rovnovážná extrakční konstanta reakce M2+(aq)+SrL2+(nb) ML2+(nb)+Sr2+(aq) v systému voda-nitrobenzen (M2+ = Mg2+, Zn2+, Mn2+; L = valinomycin; aq = vodná fáze, nb = nitrobenzenová fáze). Bylo zjištěno, že konstanty stability komplexu ML2+ v nitrobenzenu, nasyceném vodou rostou v řadě Mg2+<Mn2+<Zn2+. From extraction experiments and gamma-activity measurements, the exchange extraction constants corresponding to the general equilibrium M2+(aq)+SrL2+(nb) ML2+(nb)+Sr2+(aq) taking place in the two-phase water-nitrobenzene system (M2+ = Mg2+, Zn2+, Mn2+; L = valinomycin; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Further, the stability constants of the ML2+ complexes in water saturated nitrobenzene were calculated. They were found to increase in the order of Mg2+<Mn2+<Zn2+. From extraction experiments and gamma-activity measurements, the exchange extraction constants corresponding to the general equilibrium M2+(aq)+SrL2+(nb) ML2+(nb)+Sr2+(aq) taking place in the two-phase water-nitrobenzene system (M2+ = Mg2+, Zn2+, Mn2+; L = valinomycin; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Further, the stability constants of the ML2+ complexes in water saturated nitrobenzene were calculated. They were found to increase in the order of Mg2+<Mn2+<Zn2+.
dcterms:title
Solvent extraction of magnesium, zinc and manganese into nitrobenzene by using strontium dicarbollylcobaltate in the presence of valinomycin Solvent extraction of magnesium, zinc and manganese into nitrobenzene by using strontium dicarbollylcobaltate in the presence of valinomycin Extrakce hořčíku, zinku a manganu roztokem dikarbollylkobaltitanu strontnatého v nitrobenzenu za přítomnosti valinomycinu
skos:prefLabel
Solvent extraction of magnesium, zinc and manganese into nitrobenzene by using strontium dicarbollylcobaltate in the presence of valinomycin Extrakce hořčíku, zinku a manganu roztokem dikarbollylkobaltitanu strontnatého v nitrobenzenu za přítomnosti valinomycinu Solvent extraction of magnesium, zinc and manganese into nitrobenzene by using strontium dicarbollylcobaltate in the presence of valinomycin
skos:notation
RIV/60461373:22340/08:00020714!RIV09-MSM-22340___
n3:aktivita
n17:Z
n3:aktivity
Z(MSM4977751303), Z(MSM6046137307)
n3:cisloPeriodika
2
n3:dodaniDat
n14:2009
n3:domaciTvurceVysledku
n7:9665803
n3:druhVysledku
n16:J
n3:duvernostUdaju
n4:S
n3:entitaPredkladatele
n15:predkladatel
n3:idSjednocenehoVysledku
395848
n3:idVysledku
RIV/60461373:22340/08:00020714
n3:jazykVysledku
n13:eng
n3:klicovaSlova
physicochemical basis; biological-membranes; water-nitrobenzene; complex; ionophores; transport; stability constants; valinomycin
n3:klicoveSlovo
n5:biological-membranes n5:water-nitrobenzene n5:physicochemical%20basis n5:complex n5:ionophores n5:stability%20constants n5:valinomycin n5:transport
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[7522DB75B807]
n3:nazevZdroje
Journal of Radioanalytical and Nuclear Chemistry
n3:obor
n12:CB
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
2
n3:rokUplatneniVysledku
n14:2008
n3:svazekPeriodika
275
n3:tvurceVysledku
Makrlík, E. Vaňura, Petr
n3:wos
000257464000029
n3:zamer
n6:MSM4977751303 n6:MSM6046137307
s:issn
0236-5731
s:numberOfPages
3
n9:organizacniJednotka
22340