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Statements

Subject Item
n2:RIV%2F60461373%3A22340%2F06%3A00016851%21RIV07-MSM-22340___
rdf:type
skos:Concept n22:Vysledek
dcterms:description
Mechanisms of reactions displaying multiple steady states and/or oscillations can be categorized according to characteristic types of positive and negative feedback loops involved. These loops as well as conditions for the associated oscillatory instability are identified by using stoichiometric network analysis. Several types of experiments can be performed to classify reaction mechanisms and the role of species. Subsequently, main features of the mechanism can be deduced. A pH-oscillatory reaction of hydrogen peroxide with thiosulfate catalyzed by cupric ions (HPTCu) is taken as an example of this kind of analysis. Mechanisms of reactions displaying multiple steady states and/or oscillations can be categorized according to characteristic types of positive and negative feedback loops involved. These loops as well as conditions for the associated oscillatory instability are identified by using stoichiometric network analysis. Several types of experiments can be performed to classify reaction mechanisms and the role of species. Subsequently, main features of the mechanism can be deduced. A pH-oscillatory reaction of hydrogen peroxide with thiosulfate catalyzed by cupric ions (HPTCu) is taken as an example of this kind of analysis. Složité reakce vykazující vícenásobné ustálené stavy a/nebo oscilace lze klasifikovat podle uspořádání positivních a negativních zpětných vazeb v mechanismu reakce. Tyto zpětné vazby lze identifikovat právě pomocí analýzy stechiometrickýh sítí. Tímto způsobem je analyzována oxidace thiosíranu peroxidem vodíku v průtočném reaktoru (HPTCu reakce).
dcterms:title
Stoichiometric network analysis and classification of a pH-oscillator Stoichiometric network analysis and classification of a pH-oscillator Analýza stechiometrických sítí a klasifikace pH-oscilátorů
skos:prefLabel
Stoichiometric network analysis and classification of a pH-oscillator Analýza stechiometrických sítí a klasifikace pH-oscilátorů Stoichiometric network analysis and classification of a pH-oscillator
skos:notation
RIV/60461373:22340/06:00016851!RIV07-MSM-22340___
n3:strany
238-248
n3:aktivita
n11:P n11:Z
n3:aktivity
P(GA203/06/1269), P(GD104/03/H141), Z(MSM6046137306)
n3:dodaniDat
n18:2007
n3:domaciTvurceVysledku
n4:6542697 n4:1583980 n4:2329689 n4:5624231
n3:druhVysledku
n5:D
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n12:predkladatel
n3:idSjednocenehoVysledku
501672
n3:idVysledku
RIV/60461373:22340/06:00016851
n3:jazykVysledku
n21:eng
n3:klicovaSlova
stoichiometric network analysis; pH-oscillator; classification of a pH-oscillator; HPTCu reaction
n3:klicoveSlovo
n10:stoichiometric%20network%20analysis n10:classification%20of%20a%20pH-oscillator n10:pH-oscillator n10:HPTCu%20reaction
n3:kontrolniKodProRIV
[3410DED07C7F]
n3:mistoKonaniAkce
Bělehrad
n3:mistoVydani
Bělehrad
n3:nazevZdroje
PHYSICAL CHEMISTRY 2006 -8th International Conference on Fundamental and Applied Aspects of Physical Chemistry
n3:obor
n19:CI
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
5
n3:projekt
n13:GA203%2F06%2F1269 n13:GD104%2F03%2FH141
n3:rokUplatneniVysledku
n18:2006
n3:tvurceVysledku
Schreiber, Igor Špás, Petr Schreiberová, Lenka Voslař, Michal Pešek, Oldřich
n3:typAkce
n20:WRD
n3:zahajeniAkce
2006-09-26+02:00
n3:zamer
n17:MSM6046137306
s:numberOfPages
12
n14:hasPublisher
The Society of Physical Chemists of Serbia
n6:isbn
86-82139-27-8
n7:organizacniJednotka
22340