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Statements

Subject Item
n2:RIV%2F60461373%3A22340%2F05%3A00014444%21RIV06-GA0-22340___
rdf:type
n20:Vysledek skos:Concept
dcterms:description
An example of a chemical oscillatory system is oxidation of thiosulfate by hydrogen peroxide catalyzed by cupric ions (HPTCu reaction). Its dynamic behavior is marked by the occurrence of multiple steady states, excitability and oscillations. We study this reaction by exploring the oscillatory regime with the method of phase response. Results are presented in the form of phase transition curves (PTC). Based on the stoichiometric network analysis, all chemical oscillators can be classified into several categories. The main issue addressed here is whether is it also possible to categorize the HPTCu reaction by using phase transition curves. Phase transition curves are measured experimentally, calculated for a model of HPTCu reaction, and calculated for the prototypes of categories of chemical oscillators. By comparison of experimental PTCs with those for the prototypes, the experimental system is classified and roles of reactants are deduced. Likewise, the model of the HPTCu reaction is compared with pr An example of a chemical oscillatory system is oxidation of thiosulfate by hydrogen peroxide catalyzed by cupric ions (HPTCu reaction). Its dynamic behavior is marked by the occurrence of multiple steady states, excitability and oscillations. We study this reaction by exploring the oscillatory regime with the method of phase response. Results are presented in the form of phase transition curves (PTC). Based on the stoichiometric network analysis, all chemical oscillators can be classified into several categories. The main issue addressed here is whether is it also possible to categorize the HPTCu reaction by using phase transition curves. Phase transition curves are measured experimentally, calculated for a model of HPTCu reaction, and calculated for the prototypes of categories of chemical oscillators. By comparison of experimental PTCs with those for the prototypes, the experimental system is classified and roles of reactants are deduced. Likewise, the model of the HPTCu reaction is compared with pr Příklad chemického oscilačního systému je oxidace thiosíranu peroxidem vodíku katalyzovaná ionty mědi (reakce HPTCu). Dynamické chování této reakce se vyznačuje vícenásobnými stacionárními stavy, excitabilitou, a oscilacemi. Oscilační režim byl zkoumán pomocí metody fázového posuvu reprezentované křivkami fázového posuvu (PTC). Všechny chemické oscilátory mohou být setříděny pomocí teorie stechiometrických sítí do několika skupin. Zde řešený problém je otázka, zdali křivky PTC mohou být použity k uvedené klasifikaci. Tyto křivky jsou měřeny a počítány pro model reakce a pro prototypické modely jednotlivých kategorií chemických oscilátorů. Je provedeno srovnání a diskutována kategorizace vedoucí k návrhu zlepšení modelu..
dcterms:title
STUDY OF THE OSCILLATORY HPTCU REACTION BY THE PHASE RESPONSE METHOD. Studium oscilační reakce HPTCu pomocí metody fázové odezvy STUDY OF THE OSCILLATORY HPTCU REACTION BY THE PHASE RESPONSE METHOD.
skos:prefLabel
STUDY OF THE OSCILLATORY HPTCU REACTION BY THE PHASE RESPONSE METHOD. STUDY OF THE OSCILLATORY HPTCU REACTION BY THE PHASE RESPONSE METHOD. Studium oscilační reakce HPTCu pomocí metody fázové odezvy
skos:notation
RIV/60461373:22340/05:00014444!RIV06-GA0-22340___
n3:strany
069/1-069/10
n3:aktivita
n6:Z n6:P
n3:aktivity
P(GD104/03/H141), Z(MSM6046137306)
n3:dodaniDat
n14:2006
n3:domaciTvurceVysledku
n15:2329689 n15:6542697 n15:7696574
n3:druhVysledku
n19:D
n3:duvernostUdaju
n12:S
n3:entitaPredkladatele
n10:predkladatel
n3:idSjednocenehoVysledku
545286
n3:idVysledku
RIV/60461373:22340/05:00014444
n3:jazykVysledku
n18:eng
n3:klicovaSlova
pH-oscillation; phase transition curves
n3:klicoveSlovo
n8:phase%20transition%20curves n8:pH-oscillation
n3:kontrolniKodProRIV
[5958BEB5576B]
n3:mistoKonaniAkce
Tatranské Matliare, Slovensko
n3:mistoVydani
Bratislava
n3:nazevZdroje
Proc. of 32th International Conference of Slovak Society of Chemical Engineering.
n3:obor
n9:CI
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
3
n3:projekt
n4:GD104%2F03%2FH141
n3:rokUplatneniVysledku
n14:2005
n3:tvurceVysledku
Schreiber, Igor Bakeš, Daniel Schreiberová, Lenka
n3:typAkce
n21:WRD
n3:zahajeniAkce
2005-05-23+02:00
n3:zamer
n13:MSM6046137306
s:numberOfPages
10
n22:hasPublisher
Slovenská technická univerzita v Bratislave
n11:isbn
80-227-2224-3
n16:organizacniJednotka
22340