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Statements

Subject Item
n2:RIV%2F60461373%3A22320%2F11%3A43892486%21RIV12-MSM-22320___
rdf:type
n10:Vysledek skos:Concept
dcterms:description
Cyclic six-membered ring sulfoxides and sulfones were prepared by a stepwise in situ oxidation of the corresponding sulfides. The 1H a 13C NMR data were collected. The 1H a 13C NMR chemical shifts were calculated for geometry-optimized structures with the DFT B3LYP/6-31++G** method. The calculated 13C NMR chemical shifts induced by oxidation are in very good agreement with the experimental data. Cyclic six-membered ring sulfoxides and sulfones were prepared by a stepwise in situ oxidation of the corresponding sulfides. The 1H a 13C NMR data were collected. The 1H a 13C NMR chemical shifts were calculated for geometry-optimized structures with the DFT B3LYP/6-31++G** method. The calculated 13C NMR chemical shifts induced by oxidation are in very good agreement with the experimental data.
dcterms:title
The determination of sulfoxide configuration in six-membered rings using The determination of sulfoxide configuration in six-membered rings using
skos:prefLabel
The determination of sulfoxide configuration in six-membered rings using The determination of sulfoxide configuration in six-membered rings using
skos:notation
RIV/60461373:22320/11:43892486!RIV12-MSM-22320___
n10:predkladatel
n11:orjk%3A22320
n3:aktivita
n6:P n6:Z
n3:aktivity
P(GA203/09/1919), Z(AV0Z40550506), Z(MSM6046137308)
n3:cisloPeriodika
22
n3:dodaniDat
n14:2012
n3:domaciTvurceVysledku
n16:7708599
n3:druhVysledku
n8:J
n3:duvernostUdaju
n17:S
n3:entitaPredkladatele
n19:predkladatel
n3:idSjednocenehoVysledku
193896
n3:idVysledku
RIV/60461373:22320/11:43892486
n3:jazykVysledku
n9:eng
n3:klicovaSlova
ring sulfoxide, ring sulfone, configuration, NMR data, DFT calculation
n3:klicoveSlovo
n4:configuration n4:DFT%20calculation n4:NMR%20data n4:ring%20sulfone n4:ring%20sulfoxide
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[F4B105E37FC3]
n3:nazevZdroje
Tetrahedron: Asymmetry
n3:obor
n20:DI
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
5
n3:projekt
n18:GA203%2F09%2F1919
n3:rokUplatneniVysledku
n14:2011
n3:svazekPeriodika
2011
n3:tvurceVysledku
Janků, Josef Pohl, R. Dračínský, M. Buděšínský, M. Slavětínská, L.
n3:zamer
n15:AV0Z40550506 n15:MSM6046137308
s:issn
0957-4166
s:numberOfPages
10
n13:organizacniJednotka
22320