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Statements

Subject Item
n2:RIV%2F60461373%3A22310%2F14%3A43898438%21RIV15-GA0-22310___
rdf:type
skos:Concept n17:Vysledek
rdfs:seeAlso
http://www.sciencedirect.com/science/article/pii/S0920586114000406
dcterms:description
Nonporous and mesoporous TiO2 films of well-defined thicknesses were synthesized by the sol-gel technique with dip-coating as the deposition method. Due to the potential applications as self-cleaning surfaces and photoanodes in water splitting activities of the prepared TiO2 films were evaluated for the photodegradation of model ink 2,6-dichloroindophenol and water photooxidation in aqueous media containing an inorganic salt. Thickness and mass parameters of the TiO2 films depend linearly on the number of deposition cycles (dip-coating, drying and calcinations). Due to different viscosities of the precursor, thicknesses of a single layer of nonporous and mesoporous titania film were 65 nm and 300 nm, respectively. The crucial effect of film mass on the decolourization of solid organic films was confirmed. Photocurrent in aqueous electrolyte depends strongly on the type of conductive substrate. It is about five times lower for indium doped tin oxide (ITO) which was confirmed to be due to the increase of resistivity of ITO conductive layer during calcinations. Mesoporous films reveal significantly lower photocurrents than nonporous films which can be explained by insufficient charge transfer in mesoporous films consisting of very small mesopores. Nonporous and mesoporous TiO2 films of well-defined thicknesses were synthesized by the sol-gel technique with dip-coating as the deposition method. Due to the potential applications as self-cleaning surfaces and photoanodes in water splitting activities of the prepared TiO2 films were evaluated for the photodegradation of model ink 2,6-dichloroindophenol and water photooxidation in aqueous media containing an inorganic salt. Thickness and mass parameters of the TiO2 films depend linearly on the number of deposition cycles (dip-coating, drying and calcinations). Due to different viscosities of the precursor, thicknesses of a single layer of nonporous and mesoporous titania film were 65 nm and 300 nm, respectively. The crucial effect of film mass on the decolourization of solid organic films was confirmed. Photocurrent in aqueous electrolyte depends strongly on the type of conductive substrate. It is about five times lower for indium doped tin oxide (ITO) which was confirmed to be due to the increase of resistivity of ITO conductive layer during calcinations. Mesoporous films reveal significantly lower photocurrents than nonporous films which can be explained by insufficient charge transfer in mesoporous films consisting of very small mesopores.
dcterms:title
Photocatalytic and photoelectrochemical properties of sol-gel TiO2, film controlled thickness and porosity Photocatalytic and photoelectrochemical properties of sol-gel TiO2, film controlled thickness and porosity
skos:prefLabel
Photocatalytic and photoelectrochemical properties of sol-gel TiO2, film controlled thickness and porosity Photocatalytic and photoelectrochemical properties of sol-gel TiO2, film controlled thickness and porosity
skos:notation
RIV/60461373:22310/14:43898438!RIV15-GA0-22310___
n4:aktivita
n16:P
n4:aktivity
P(GAP108/12/2104)
n4:cisloPeriodika
červenec
n4:dodaniDat
n15:2015
n4:domaciTvurceVysledku
n5:8453047 n5:3910245 n5:7285329
n4:druhVysledku
n19:J
n4:duvernostUdaju
n8:S
n4:entitaPredkladatele
n7:predkladatel
n4:idSjednocenehoVysledku
36470
n4:idVysledku
RIV/60461373:22310/14:43898438
n4:jazykVysledku
n14:eng
n4:klicovaSlova
Photocurrent; 2,6-Dichloroindophenol; Porosity; Thickness; Sol gel; film
n4:klicoveSlovo
n9:2 n9:Photocurrent n9:Porosity n9:Thickness n9:6-Dichloroindophenol n9:film n9:Sol%20gel
n4:kodStatuVydavatele
NL - Nizozemsko
n4:kontrolniKodProRIV
[9A8CF6CED57B]
n4:nazevZdroje
Catalysis Today
n4:obor
n18:CF
n4:pocetDomacichTvurcuVysledku
3
n4:pocetTvurcuVysledku
6
n4:projekt
n20:GAP108%2F12%2F2104
n4:rokUplatneniVysledku
n15:2014
n4:svazekPeriodika
230
n4:tvurceVysledku
Krýsová, H. Morozová, M. Zlámal, Martin Baudys, Michal Krýsa, Josef Klusoň, P.
n4:wos
000333800300002
s:issn
0920-5861
s:numberOfPages
6
n11:doi
10.1016/j.cattod.2014.01.008
n13:organizacniJednotka
22310