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Statements

Subject Item
n2:RIV%2F60461373%3A22310%2F14%3A43898138%21RIV15-MSM-22310___
rdf:type
n11:Vysledek skos:Concept
dcterms:description
Thiophene- and furan-derived aminocarbene complexes are regioselectively lithiated by BuLi at position 5, while lithiated aminocarbenes containing pyrrole or phenyl groups can be obtained by a bromine to lithium exchange reaction using BuLi. Such prepared lithiated aminocarbene complexes react with alkyl halides, aldehydes, ketones, acyl chlorides, and DMF, giving high yields of functionalized aminocarbene complexes hardly accessible by other ways. Thiophene- and furan-derived aminocarbene complexes are regioselectively lithiated by BuLi at position 5, while lithiated aminocarbenes containing pyrrole or phenyl groups can be obtained by a bromine to lithium exchange reaction using BuLi. Such prepared lithiated aminocarbene complexes react with alkyl halides, aldehydes, ketones, acyl chlorides, and DMF, giving high yields of functionalized aminocarbene complexes hardly accessible by other ways.
dcterms:title
Lithiation of chromium and tungsten aminocarbene complexes: An easy approach to functionalized aminocarbene complexes. Lithiation of chromium and tungsten aminocarbene complexes: An easy approach to functionalized aminocarbene complexes.
skos:prefLabel
Lithiation of chromium and tungsten aminocarbene complexes: An easy approach to functionalized aminocarbene complexes. Lithiation of chromium and tungsten aminocarbene complexes: An easy approach to functionalized aminocarbene complexes.
skos:notation
RIV/60461373:22310/14:43898138!RIV15-MSM-22310___
n3:aktivita
n4:P
n3:aktivity
P(LC06070)
n3:cisloPeriodika
12
n3:dodaniDat
n5:2015
n3:domaciTvurceVysledku
n9:6577474 n9:6702198 n9:5078008 n9:8767769
n3:druhVysledku
n6:J
n3:duvernostUdaju
n13:S
n3:entitaPredkladatele
n18:predkladatel
n3:idSjednocenehoVysledku
26380
n3:idVysledku
RIV/60461373:22310/14:43898138
n3:jazykVysledku
n19:eng
n3:klicovaSlova
ALKYNES; DIANION; DERIVATIVES; (AMINOCARBENE)CHROMIUM(0) COMPLEXES; ORGANIC-SYNTHESIS; DIASTEREOSELECTIVE CYCLOPROPANATION; ELECTRON-DEFICIENT ALKENES; FISCHER CARBENE COMPLEXES
n3:klicoveSlovo
n14:DERIVATIVES n14:ORGANIC-SYNTHESIS n14:%28AMINOCARBENE%29CHROMIUM%280%29%20COMPLEXES n14:DIANION n14:FISCHER%20CARBENE%20COMPLEXES n14:DIASTEREOSELECTIVE%20CYCLOPROPANATION n14:ALKYNES n14:ELECTRON-DEFICIENT%20ALKENES
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[62D3A9914C4C]
n3:nazevZdroje
Organometallics
n3:obor
n12:CC
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
4
n3:projekt
n15:LC06070
n3:rokUplatneniVysledku
n5:2014
n3:svazekPeriodika
33
n3:tvurceVysledku
Tobrman, Tomáš Dvořák, Dalimil Jurásková, Ivana Váňová, Hana
n3:wos
000337936800007
s:issn
0276-7333
s:numberOfPages
7
n16:doi
10.1021/om500182p
n10:organizacniJednotka
22310