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Statements

Subject Item
n2:RIV%2F60461373%3A22310%2F14%3A43898101%21RIV15-GA0-22310___
rdf:type
n6:Vysledek skos:Concept
dcterms:description
A new type of calixarene-based receptor designed for the recognition of chiral anions was prepared by the introduction of (S)-2-methylbutan-1-ol moieties into the lower rim of calixarene. The immobilization of calixarene skeleton in the 1,3-alternate conformation enabled the construction of a cavity consisting of preorganised ureido functions and chiral substituents in close proximity. This cavity is capable of chiral discrimination of selected anions as demonstrated on d- and l-phenylalaninates. A new type of calixarene-based receptor designed for the recognition of chiral anions was prepared by the introduction of (S)-2-methylbutan-1-ol moieties into the lower rim of calixarene. The immobilization of calixarene skeleton in the 1,3-alternate conformation enabled the construction of a cavity consisting of preorganised ureido functions and chiral substituents in close proximity. This cavity is capable of chiral discrimination of selected anions as demonstrated on d- and l-phenylalaninates.
dcterms:title
Recognition of chiral anions using calix[4]arene-based ureido receptors in the 1,3-alternate conformation Recognition of chiral anions using calix[4]arene-based ureido receptors in the 1,3-alternate conformation
skos:prefLabel
Recognition of chiral anions using calix[4]arene-based ureido receptors in the 1,3-alternate conformation Recognition of chiral anions using calix[4]arene-based ureido receptors in the 1,3-alternate conformation
skos:notation
RIV/60461373:22310/14:43898101!RIV15-GA0-22310___
n3:aktivita
n19:P
n3:aktivity
P(GA13-21704S), P(IAAX08240901)
n3:cisloPeriodika
2
n3:dodaniDat
n12:2015
n3:domaciTvurceVysledku
n4:5642272 n4:1751220 n4:7515367 n4:4338820 n4:4227255
n3:druhVysledku
n16:J
n3:duvernostUdaju
n9:S
n3:entitaPredkladatele
n5:predkladatel
n3:idSjednocenehoVysledku
41602
n3:idVysledku
RIV/60461373:22310/14:43898101
n3:jazykVysledku
n15:eng
n3:klicovaSlova
Anion recognition; Chiral receptor; NMR titration; Alkylation; Calixarene
n3:klicoveSlovo
n8:Alkylation n8:Chiral%20receptor n8:Anion%20recognition n8:NMR%20titration n8:Calixarene
n3:kodStatuVydavatele
IE - Irsko
n3:kontrolniKodProRIV
[41930B453CD0]
n3:nazevZdroje
Tetrahedron
n3:obor
n10:CC
n3:pocetDomacichTvurcuVysledku
5
n3:pocetTvurcuVysledku
7
n3:projekt
n11:IAAX08240901 n11:GA13-21704S
n3:rokUplatneniVysledku
n12:2014
n3:svazekPeriodika
70
n3:tvurceVysledku
Botha, Filip Vrzal, Lukáš Budka, Jan Hudeček, Oldřich Lhoták, Pavel Eigner, Václav Císařová, Ivana
n3:wos
000330816000043
s:issn
0040-4020
s:numberOfPages
7
n17:doi
10.1016/j.tet.2013.11.030
n13:organizacniJednotka
22310