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Statements

Subject Item
n2:RIV%2F60461373%3A22310%2F14%3A43897968%21RIV15-GA0-22310___
rdf:type
n3:Vysledek skos:Concept
rdfs:seeAlso
http://dx.doi.org/10.1016/j.tetasy.2014.08.011
dcterms:description
Only four types of dimeric precursors [RuCl2(éta6-arene)]2 for the synthesis of Noyori's half sandwich diamine catalysts [RuCl(TsDPEN)(éta6-arene)] are commercially available, yet so far no study has tried to systematically evaluate how these systems perform during the asymmetric transfer hydrogenation of various 3,4-dihydroisoquinolines (i.e., the typical substrates for Noyori asymmetric transfer hydrogenation benchmarking). Experiments combined with molecular modeling allowed us to assess their properties and formulate a hypothesis clarifying the difference in enantioselectivity of these systems. Only four types of dimeric precursors [RuCl2(éta6-arene)]2 for the synthesis of Noyori's half sandwich diamine catalysts [RuCl(TsDPEN)(éta6-arene)] are commercially available, yet so far no study has tried to systematically evaluate how these systems perform during the asymmetric transfer hydrogenation of various 3,4-dihydroisoquinolines (i.e., the typical substrates for Noyori asymmetric transfer hydrogenation benchmarking). Experiments combined with molecular modeling allowed us to assess their properties and formulate a hypothesis clarifying the difference in enantioselectivity of these systems.
dcterms:title
The role of the aromatic ligand in the asymmetric transfer hydrogenation of the CN double bond; length as m-dashN bond on Noyori's chiral Ru catalysts The role of the aromatic ligand in the asymmetric transfer hydrogenation of the CN double bond; length as m-dashN bond on Noyori's chiral Ru catalysts
skos:prefLabel
The role of the aromatic ligand in the asymmetric transfer hydrogenation of the CN double bond; length as m-dashN bond on Noyori's chiral Ru catalysts The role of the aromatic ligand in the asymmetric transfer hydrogenation of the CN double bond; length as m-dashN bond on Noyori's chiral Ru catalysts
skos:notation
RIV/60461373:22310/14:43897968!RIV15-GA0-22310___
n5:aktivita
n13:P
n5:aktivity
P(GAP106/12/1276)
n5:cisloPeriodika
18-19
n5:dodaniDat
n19:2015
n5:domaciTvurceVysledku
n6:9615520 n6:9453156 n6:2030713 n6:5882338 n6:6401880
n5:druhVysledku
n14:J
n5:duvernostUdaju
n17:S
n5:entitaPredkladatele
n15:predkladatel
n5:idSjednocenehoVysledku
43197
n5:idVysledku
RIV/60461373:22310/14:43897968
n5:jazykVysledku
n8:eng
n5:klicovaSlova
arene; imines; ruthenium
n5:klicoveSlovo
n7:ruthenium n7:imines n7:arene
n5:kodStatuVydavatele
IE - Irsko
n5:kontrolniKodProRIV
[7DF235B92537]
n5:nazevZdroje
Tetrahedron Asymmetry
n5:obor
n20:CC
n5:pocetDomacichTvurcuVysledku
5
n5:pocetTvurcuVysledku
7
n5:projekt
n10:GAP106%2F12%2F1276
n5:rokUplatneniVysledku
n19:2014
n5:svazekPeriodika
25
n5:tvurceVysledku
Vilhanová, Beáta Kuzma, Marek Šot, Petr Zápal, Jakub Kačer, Petr Václavík, Jiří Pecháček, Jan
n5:wos
000343847700014
s:issn
0957-4166
s:numberOfPages
6
n9:doi
10.1016/j.tetasy.2014.08.011
n18:organizacniJednotka
22310