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Statements

Subject Item
n2:RIV%2F60461373%3A22310%2F14%3A43897963%21RIV15-GA0-22310___
rdf:type
skos:Concept n14:Vysledek
rdfs:seeAlso
http://dx.doi.org/10.3390/molecules19066987
dcterms:description
The asymmetric transfer hydrogenation (ATH) of imines catalyzed by the Noyori-Ikariya [RuCl(éta6-arene)(N-arylsulfonyl-DPEN)] (DPEN = 1,2-diphenylethylene-1,2-diamine) half-sandwich complexes is a research topic that is still being intensively developed. This article focuses on selected aspects of this catalytic system. First, a great deal of attention is devoted to the N-arylsulfonyl moiety of the catalysts in terms of its interaction with protonated imines (substrates) and amines (components of the hydrogen-donor mixture). The second part is oriented toward the role of the éta6-coordinated arene. The final part concerns the imine substrate structural modifications and their importance in connection with ATH. Throughout the text, the summary of known findings is complemented with newly-presented ones, which have been approached both experimentally and computationally. The asymmetric transfer hydrogenation (ATH) of imines catalyzed by the Noyori-Ikariya [RuCl(éta6-arene)(N-arylsulfonyl-DPEN)] (DPEN = 1,2-diphenylethylene-1,2-diamine) half-sandwich complexes is a research topic that is still being intensively developed. This article focuses on selected aspects of this catalytic system. First, a great deal of attention is devoted to the N-arylsulfonyl moiety of the catalysts in terms of its interaction with protonated imines (substrates) and amines (components of the hydrogen-donor mixture). The second part is oriented toward the role of the éta6-coordinated arene. The final part concerns the imine substrate structural modifications and their importance in connection with ATH. Throughout the text, the summary of known findings is complemented with newly-presented ones, which have been approached both experimentally and computationally.
dcterms:title
Experimental and Theoretical Perspectives of the Noyori-Ikariya Asymmetric Transfer Hydrogenation of Imines Experimental and Theoretical Perspectives of the Noyori-Ikariya Asymmetric Transfer Hydrogenation of Imines
skos:prefLabel
Experimental and Theoretical Perspectives of the Noyori-Ikariya Asymmetric Transfer Hydrogenation of Imines Experimental and Theoretical Perspectives of the Noyori-Ikariya Asymmetric Transfer Hydrogenation of Imines
skos:notation
RIV/60461373:22310/14:43897963!RIV15-GA0-22310___
n3:aktivita
n19:P
n3:aktivity
P(GAP106/12/1276), P(LO1215)
n3:cisloPeriodika
6
n3:dodaniDat
n11:2015
n3:domaciTvurceVysledku
n10:2030713 n10:7643993 n10:6401880 n10:9453156 n10:9615520 n10:5882338
n3:druhVysledku
n17:J
n3:duvernostUdaju
n6:S
n3:entitaPredkladatele
n18:predkladatel
n3:idSjednocenehoVysledku
15793
n3:idVysledku
RIV/60461373:22310/14:43897963
n3:jazykVysledku
n15:eng
n3:klicovaSlova
DFT; arene; sulfonyl; ligand; imine; asymmetric hydrogenation; ruthenium
n3:klicoveSlovo
n4:asymmetric%20hydrogenation n4:ligand n4:imine n4:sulfonyl n4:DFT n4:ruthenium n4:arene
n3:kodStatuVydavatele
CH - Švýcarská konfederace
n3:kontrolniKodProRIV
[BBB8C4820045]
n3:nazevZdroje
Molecules
n3:obor
n13:CC
n3:pocetDomacichTvurcuVysledku
6
n3:pocetTvurcuVysledku
7
n3:projekt
n8:GAP106%2F12%2F1276 n8:LO1215
n3:rokUplatneniVysledku
n11:2014
n3:svazekPeriodika
19
n3:tvurceVysledku
Václavík, Jiří Matuška, Ondřej Pecháček, Jan Kačer, Petr Šot, Petr Kuzma, Marek Vilhanová, Beáta
n3:wos
000338586700006
s:issn
1420-3049
s:numberOfPages
21
n20:doi
10.3390/molecules19066987
n16:organizacniJednotka
22310