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Statements

Subject Item
n2:RIV%2F60461373%3A22310%2F13%3A43895708%21RIV14-MSM-22310___
rdf:type
skos:Concept n12:Vysledek
dcterms:description
The solubility of nickel and cobalt oxides in ZnO nanoparticles was explored using the equilibrium thermodynamic approach. The equilibrium conditions were derived for the binary system ZnO-TMO (TM = Ni or Co) consists of two different spherical nanoparticles, one comprising the wurtzite (Zn1-xTMx)O(wz) solid solution and the second the rocksalt (TM1-xZnx)O(rs) solid solutions. Thermodynamic parameters for both phases were evaluated from bulk phase diagrams and the surface energy terms were included. Calculations of phase boundaries between the wurtzite and the rocksalt solid solutions reveal significant rise of the TM content in wurtzite phase. At the same time, the solubility of ZnO in rocksalt phase decreases. This behavior is more obvious for nanoparticles less than 5 nm in diameter and becomes more evident with increasing temperature. These results are in qualitative agreement with published experimental data. The solubility of nickel and cobalt oxides in ZnO nanoparticles was explored using the equilibrium thermodynamic approach. The equilibrium conditions were derived for the binary system ZnO-TMO (TM = Ni or Co) consists of two different spherical nanoparticles, one comprising the wurtzite (Zn1-xTMx)O(wz) solid solution and the second the rocksalt (TM1-xZnx)O(rs) solid solutions. Thermodynamic parameters for both phases were evaluated from bulk phase diagrams and the surface energy terms were included. Calculations of phase boundaries between the wurtzite and the rocksalt solid solutions reveal significant rise of the TM content in wurtzite phase. At the same time, the solubility of ZnO in rocksalt phase decreases. This behavior is more obvious for nanoparticles less than 5 nm in diameter and becomes more evident with increasing temperature. These results are in qualitative agreement with published experimental data.
dcterms:title
Nanosizing as a way to enhanced solubility of transition metals in ZnO Nanosizing as a way to enhanced solubility of transition metals in ZnO
skos:prefLabel
Nanosizing as a way to enhanced solubility of transition metals in ZnO Nanosizing as a way to enhanced solubility of transition metals in ZnO
skos:notation
RIV/60461373:22310/13:43895708!RIV14-MSM-22310___
n12:predkladatel
n14:orjk%3A22310
n3:aktivita
n16:I
n3:aktivity
I
n3:cisloPeriodika
3
n3:dodaniDat
n17:2014
n3:domaciTvurceVysledku
n10:5395097 n10:9559043 n10:6541690
n3:druhVysledku
n15:J
n3:duvernostUdaju
n9:S
n3:entitaPredkladatele
n11:predkladatel
n3:idSjednocenehoVysledku
90617
n3:idVysledku
RIV/60461373:22310/13:43895708
n3:jazykVysledku
n19:eng
n3:klicovaSlova
Thermodynamics; Solubility; Transition metals; Zinc oxide; Nanoparticles
n3:klicoveSlovo
n4:Nanoparticles n4:Solubility n4:Transition%20metals n4:Zinc%20oxide n4:Thermodynamics
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[F44F6E3AFDB3]
n3:nazevZdroje
Journal of Nanoparticle Research
n3:obor
n18:CF
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
4
n3:rokUplatneniVysledku
n17:2013
n3:svazekPeriodika
15
n3:tvurceVysledku
Kamrádek, Michal Sedmidubský, David Leitner, Jindřich Voňka, Petr
n3:wos
000318551300005
s:issn
1388-0764
s:numberOfPages
9
n13:doi
10.1007/s11051-013-1450-7
n6:organizacniJednotka
22310